Variational calculations of the 25 lowest energy vibrational states of the Ne2SH and Ne2OH (A (2)Sigma(+)) complexes are performed using potentials that are obtained by the pairwise addition of accurate neon dimer and Ne.XH potentials. The Ne2XH complexes are able to sample several local minima in their respective potentials at relatively low internal energies. Consequently, both complexes display average densities of states that exceed one vibrational state per cm-1 in the energy regime covered by this study. In spite of this, all of the calculated states are assigned to specific vibrational excitations, based on a structure of the complex that corresponds to one of the minima on the potential, and all of the minima are found to support progressions of bending states. In most cases, it is found that the wave functions have most of their amplitude in one of the potential minima, but the couplings between zero-order states that are localized in different minima increase as the internal energy is increased. The extent of mixing is found to depend on the symmetry of the wave functions with respect to the interchange of the two neon atoms. Effects of the differences in the anisotropies of the Ne.OH and Ne.SH potentials on the vibrational energies and wave functions are also investigated.