화학공학소재연구정보센터
Journal of Chemical Physics, Vol.117, No.4, 1567-1574, 2002
Singlet-triplet conversion induced by external magnetic field in gaseous oxalylfluoride excited to different single rotational levels of the (A)over-tilde(1)A(u) state. I. Excitation to the SRLs of the 8(1) vibronic level
Fluorescence decay of the rotationally cooled oxalylfluoride excited to the different single rotational levels of the (A) over tilde (1)A(u)(8(1)) state was measured as a function of an external magnetic field. On excitation to this level, the dynamics in both zero and nonzero fields may be described using the intermediate-molecule limit, with the fluorescence exhibiting biexponential decay. The fast component decay rate constant is the field-independent parameter, while that of the slow component depends on the magnetic field strength. The results obtained were explained by the indirect (electronic and nuclear-spin-decoupling) mechanism, proposed earlier.