화학공학소재연구정보센터
Journal of Chemical Physics, Vol.117, No.4, 1708-1713, 2002
Temperature dependence of vibrational relaxation in liquid H2O
We have determined the lifetime of the OH-stretch vibration in pure liquid water as a function of temperature using femtosecond mid-infrared pump-probe spectroscopy. The lifetime T-1 increases from 260+/-18 fs at T=298 K to 320+/-18 fs at T=358 K. The increase in lifetime with temperature can be quantitatively explained from the decrease in overlap resonance between the OH-stretch vibration and the overtone of the H-O-H bending mode.