Femtosecond multicolor pump-probe spectroscopy on the prototypical intramolecular electron-transfer compound ([(NH3)(5)RuNCRu(CN)(5)](-); RuRu) in aqueous solution is reported for the first time with sufficient time resolution and spectral coverage to monitor the complete spectral dynamics. From the dynamic absorption spectrum, constructed from the pump-probe data obtained over a wide range of probe wavelengths (5701300 nm), accurate measurement of the electron transfer (ET) time (MET) have been obtained by a global analysis of the data. The data have lead to new insights on the role of solvent and solute nuclear motions in the ET process. Additionally, pump-probe experiments with variable wavelength pump pulses have revealed the presence of a pump wavelength-dependent dynamic feature at early time, which has been assigned to stimulated emission from nonequilibrium excited states.