Langmuir, Vol.18, No.9, 3423-3424, 2002
Exclusion volume term in the inhomogeneous Poisson-Boltzmann theory for high surface charge
A restricted primitive model electrolyte in the neighborhood of a uniformly charged plane electrode is investigated at high surface charge using an improved Poisson-Boltzmann theory. A layering of counterions is found in agreement with Monte Carlo simulations.