화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.86, No.5, 1047-1056, 2002
Modeling of "living" free-radical polymerization processes. II. Tubular reactors
A tubular reactor model for "living" free-radical polymerization is developed in this study. The model may be used as a tool to design efficient processes for tailored polymers from "living" free-radical polymerization. Examples presented include preparing bimodal polymers and copolymers of n-butyl acrylate and styrene. Residence time distribution effects on polymer properties are investigated by varying the Peclet number, to show the degree of backmixing that adversely affects polymer properties.