CeO2-Al2O3 mixed oxides with different CeO2 loading (in the range of 0.5-12 wt.%) were prepared by wetness impregnation of alumina with aqueous solution of di-ammonium hexanitrate cerate (NH4)(2)[Ce(NO3)(6)]. The samples after calcination at 773 and 1073 K were characterized by different techniques, using X-ray diffraction (XRD), UV-VIS diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and temperature-programmed reduction (TPR). It is shown that different types of cerium oxide species are formed on the surface depending on the amount of CeO2 and temperature of calcination of the samples. XRD showed the formation of nanocrystallites of ceria on alumina surface when the amount of CeO2 is higher than 6 wt.%; at lower concentrations ceria was found to be amorphous. The ceria loading lower than 6 wt.% stabilizes the textural properties of alumina. At loading of I wt.% of CeO2 XPS spectra reveals the presence of a strong interaction between ceria and alumina leading to a formation of superficial CeAlO3-like phase. TPR results show that well dispersed CeO2 particles present on the surface of alumina form CeAlO3 at temperature of reduction in the range of 873-993 K, while for the reduction of CeO2 crystallites, a higher temperature of reduction of 1190 K is needed.