화학공학소재연구정보센터
Journal of Applied Electrochemistry, Vol.32, No.4, 389-394, 2002
Influence of an electrochemically generated gas phase on pressure drop in a three-dimensional electrode and an inert bed
The influence of an electrochemically generated gas phase on the pressure drop in a three-dimensional electrode and an inert bed has been investigated. The electrode was composed of silvered glass particles, whereas the inert bed was composed of glass particles of the same diameter. During water electrolysis smaller gas bubbles are generated than by introducing gas into the system by means of a fluid distributor. Electrochemically generated bubbles with the liquid phase circulate upward through the electrode and the inert bed. The pressure drop for a monophase fluid was measured, as well as the change of pressure drop with time in the electrode and the inert bed for two-phase flow of fluid through an electrochemical cell. The steady and unsteady periods of the change of pressure drop have been discussed. Experiments were carried out at different electrolyte velocities and for different current densities. Higher electrolyte velocities cause an increase in the pressure drop in both beds. Also, increased current density causes an increase in gas evolution intensity at the electrode thereby increasing the pressure drop in both beds. A mathematical model describing the change of pressure drop with time has been proposed. The proposed model showed good agreement with experimental results as well as the results from the literature.