A new bulky pendent bis(ether anhydride), 1,1-bis[4-(4-dicarboxyphenoxy)phenyl]-4-phenylcyclohexane dianhydride, was prepared in three steps, starting from the nitrodisplacement of 1,1-bis(4-hydroxyphenyl)-4-phenylcyclohexane with 4-nitrophthalonitrile to form bis(ether dinitrile), followed by alkaline hydrolysis of the bis(ether dinitrile) and subsequent dehydration of the resulting bis(ether diacid). A series of now poly(ether imide)s were prepared from the bis(ether anhydride) with various diamines by a conventional two-stage synthesis including polyaddition and subsequent chemical cyclodehydration. The resulting poly(ether imide)s had inherent viscosities of 0.50-0.73 dL g(-1). The gel permeation chromatography measurements revealed that the polymers had number-average and weight-average molecular weights of up to 57,000 and 130,000, respectively. All the polymers showed typical amorphous diffraction patterns. All of the poly(ether imide)s showed excellent solubility in comparison with the other polyimides derived from adamantane, norbornane, cyclododecane, and methanohexahydroindane and were readily dissolved in various solvents such as N-methyl-2-pyrrolidinone, N,N-dimethylacetamide (DMAc), N,N-dimethylformamide, pyridine, cyclohexanone, tetrahydrofuran, and even chloroform. These polymers had glass-transition temperatures of 226-255 degreesC. Most of the polymers could be dissolved in chloroform in as high as a 30 wt % concentration. Thermogravimetric analysis showed that all polymers were stable up to 450 degreesC, with 10% weight losses recorded from 458 to 497 degreesC in nitrogen. These transparent, tough, and flexible polymer films could be obtained by solution casting from DMAc solutions. These polymer films had tensile strengths of 79-103 MPa and tensile moduli of 1.5-2.1 GPa.