화학공학소재연구정보센터
Polymer Engineering and Science, Vol.42, No.5, 940-950, 2002
Effect of melt temperature and skin-core morphology on the mechanical performance of nylon 6
The crystalline texture and mechanical (tensile and flexural) properties of injection molded nylon 6 were evaluated to understand the influence of the melt temperature (T-mlt), one of the key-processing variables. The mechanical properties are found to be sensitive to T-mlt only below similar to250degreesC. Rapid quenching of the surface produces a skin with lower crystallinity than the core, which cools more slowly; because of this difference in the rate of cooling, the crystalline component in the skin is rich in gamma and that in the core is rich in a. The thickness of this skin decreases from about 1.25 mm to 0.75 mm as T-mlt increases from 225degreesC to 310degreesC. Higher tensile strength at yield, lower elongation at break and higher flexural strength were observed in specimens molded at lower T-mlt These characteristics are associated with thicker and less ordered skin, and a lower crystallinity core. The role of the T-mlt on microstructure and mechanical properties of injection molded nylon 6, the development of skin-core morphology, and the role of the residual stresses in the core are discussed.