Solid State Ionics, Vol.150, No.3-4, 373-382, 2002
Current-voltage characteristic of BaTiO3-delta in its mixed n/p regime under oxygen potential gradients
Current (I)-voltage (V) characteristic under oxygen potential gradients was experimentally examined on single crystal BaTiO3-delta in its mixed ion/electron/hole regime at 1000 degreesC. The variation of I vs. V appears similar to that of an n/p junction, but with the limiting slope (dI/dV) approaching the maximum and minimum possible equilibrium conductances in the given oxygen potential gradient as increasing forward and reverse bias, respectively. This characteristic has been precisely traced theoretically by using the partial ionic and electronic conductivities of BaTiO3-delta as measured against uniform oxygen chemical potential in equilibrium state. The nonlinear characteristic is attributed to the redistribution of oxygen chemical potential that is caused by a non-vanishing gradient of the ionic transference number of the oxide under the given oxygen potential gradient. It is demonstrated that the bulk transport properties of a mixed conductor may be tailored by terminal voltage in a chemical potential gradient.
Keywords:BaTiO3;I-V characteristic;mass/charge transport;mixed ionic electronic conductor;oxygen potential gradient