화학공학소재연구정보센터
Desalination, Vol.149, No.1-3, 163-167, 2002
Treatment of spent emulsion from a cable factory by an integrated UF/NF membrane system
The potential of using the integrated membrane system based on ultrafiltration (UF) and nanofiltration (NF) in purification of effluents from a cable factory was investigated. The UF experiments were performed using tubular membranes taking into consideration the composition of the treated effluents. The UF process was carried out within the range of parameters recommended for oil emulsion. The application of UF membranes with MWCO of 100 kDa results in the complete rejection of suspended solids and the retention of oil and lubricants at a level of 99%. The UF membranes employed exhibit a 96% passage of copper ions, which is the major component of spent emulsion. The average permeate flux during the UF pretreatment of wastewater produce during copper wire drawing amounts 45 l/m(2)h for the transmembrane pressure of 2 bar. The resulting UF permeate was further purified by NF to achieve the retention of remaining pollutants (oil and lubricants) and to reduce the content of copper ions. As a result of the NF process, the content of organic compounds in the permeate determined as TOC was below 1 mg/dm(3), and the rejection of copper ions obtained with the AFC30 membrane was at a level of 92%. The quality of permeate obtained by the application of an UF/NF integrated membrane system allows the direct reuse of treated water for fresh emulsion top up.