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Journal of Materials Science, Vol.37, No.21, 4507-4516, 2002
Review: the microhardness of non-crystalline materials
Hardness is defined as a phenomenological measure of resistance of a material to shear stresses under local volume compression. It is shown that this definition may serve as a theoretical basis for existing empirical relationships between the Vickers microhardness H-V and the various phenomenological, packing density-sensitive parameters of non-crystalline materials, including among them, the internal pressure, the glass transition temperature T-g, the excess enthalpy, and the free volume fraction at T-g.