In this study, experiments of a nickel electroplating were performed by a conductive emulsion solution of CO₂/electrolyte/surfactant/entrainer in the supercritical nanoplating system to investigate the effect of the resistivity on plating properties. Resistivity values decreased 60, 35, and 22 Ω at 20, 30, 50 wt% electrolyte, respectively, and over 60 wt%, the resistivity value was kept constant at 20 Ω. Surface properties of nickel film electroplated by the emulsion solution with 60 wt% electrolyte at 8 MPa was better than that at atmospheric pressure.