Journal of Physical Chemistry A, Vol.107, No.3, 346-350, 2003
Effect of electrolyte diffusion on the growth of NaCl particles by water vapour condensation
The hygroscopic growth of NaCl particles was investigated both experimentally and theoretically. Straightforward experiments done with a humidity controlled microbalance show that a macroscopic time (hours to days) is required before the final (equilibrium) size is reached. The developed model shows that the droplets are not homogeneous salt solutions and that a finite liquid phase diffusion resistance exists. This is clearly evident from the experimental data also: the initial stage of growth shows a linear mass growth in time. This would not be possible without the liquid-phase resistance. It was also possible to determine the liquid-phase diffusion coefficient. Although the value depends on composition and temperature, the best fit with experimental data was obtained by using a value of 1.5 x 10(-9) m(2)/s, which agrees well with available experimental data for strong NaCl-water electrolytes.