화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.11, No.1, 69-72, February, 2003
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The First Synthesis of a Transition Metal-Catalyzed Homopolymer Having Pendent t-Boc-Protected Quinizarin for Patterned Fluorescence Images
Jimmy Yoo, Jae-Hyoung Lee1, Iwhan Cho1, Kwang-Duk Ahn2, and Jong-Man Kim3, †
  • Department of Chemistry, Korea Advanced Institute of Science and Technology, Yusong-ku, Taejon 305-701, Korea
  • 1Department of Advanced Materials Engineering, Korea Advanced Institute of Science and Technology, Yusong-ku, Taejon 305-701, Korea
  • 2Functional Polymer Laboratory, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul 130-650, Korea
  • 3Department of Chemical Engineering, Hanyang University, 17 Haengdang-dong, Seongdong-gu, Seoul 133-791, Korea
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A homopolymer having pendent t-Boc-protected quinizarin moieties has been prepared for patterned fluorescence images. The homopolymer P{t-BQN (2-norbornenylmethyl di-tert-butoxycarbonylquinizarin)} 5 was prepared by palladium-catalyzed addition polymerization. The t-Boc-protecting groups of the polymer were efficiently removed during chemical amplification process and revealed original properties of quinizarin, allowing patterned fluorescence images in the polymer film.
Keywords:patterned fluorescence image;homopolymer;chemical amplification;addition polymerization
  1. Gaylord NG, Deshpande AB, Mandal BM, Martan M, J. Macromol. Sci.-Chem., A11, 1053 (1977)
  2. Gaylord NG, Mandal BM, Martan M, J. Polym. Sci. C: Polym. Lett., 14, 555 (1976)
  3. Hall HK, Padias AB, Accounts Chem. Res., 30, 322 (1977)
  4. Okoroanyanwu U, Shimokawa T, Byers J, Willson UG, Chem. Mater., 10, 3319 (1998) 
  5. Ivin KJ, Mol JC, Olefin Methathesis and Metathesis Polymerization, Academic Press, Inc., San Diego, References therein (1997)
  6. Nguyen ST, Grubbs RH, Ziller JW, J. Am. Chem. Soc., 115, 9858 (1993) 
  7. Liaw DJ, Tsai CH, Polymer, 41(8), 2773 (2000) 
  8. Peruch F, Cramail H, Deffieux A, Macromol. Chem. Phys., 199, 2221 (1998) 
  9. Haselwander TFA, Heitz W, Maskos M, Macromol. Rapid Commun., 18, 689 (1997) 
  10. Peucker U, Heitz W, Macromol. Rapid Commun., 19, 159 (1998)
  11. Mast C, Krieger M, Dehnicke K, Greiner A, Macromol. Rapid Commun., 20, 232 (1999) 
  12. Arndt M, Beulich I, Macromol. Chem. Phys., 199, 1221 (1998)
  13. Kim JM, Chang TE, Kang JH, Park KH, Han DK, Han KD, Angew. Chem.-Int. Edit., 39, 1780 (2000) 
  14. Kim JM, Shin HY, Park KH, Kim TH, Ju SY, Han DK, Ahn KD, Macromolecules, 34(13), 4291 (2001) 
  15. Lee JH, Cho I, Ahn KD, Kim JM, Chem. Lett., 716 (2001) 
  16. Kim JM, Kang JH, Han DK, Lee CW, Ahn KD, Chem. Mater., 10, 2332 (1998) 
  17. Kim JM, Chang TE, Kang JH, Han DK, Ahn KD, Adv. Mater., 11, 1499 (1999) 
  18. Kim JM, Kim JY, Kim TH, Han DK, Ahn KD, Chem. Lett., 360 (2000) 
  19. Kim JM, Chang TE, Park RH, Kim DJ, Han DK, Ahn KD, Chem. Lett., 712 (2000) 
  20. Lewis CE, J. Org. Chem., 35, 2938 (1970)
  21. Frechet JMJ, Eichler E, Ito H, Willson CG, Polymer, 24, 995 (1983) 
  22. Reichmanis E, Houlihan FM, Nalamasu O, Neenan TX, Chem. Mater., 3, 394 (1991) 
  23. Macdonald SA, Willson CG, Frechet JMJ, Accounts Chem. Res., 27, 151 (1994) 
  24. Niu QJ, Frechet JMJ, Angew. Chem.-Int. Edit., 37, 667 (1998)