The morphology of woven oriented polypropylene tapes and fibres has been studied both before and after processing by hot compaction. In this technique bundles of oriented tapes or fibres are subjected to suitable conditions of temperature and pressure so that just sufficient of each tape or fibre is selectively melted; on cooling, this material recrystallizes to bind the whole structure together. Three different polymers were studied, woven into various individual weave styles, in relation to optimum processing conditions. The weave style, the adhesion between neighbouring interfaces after compaction and the direction of crack propagation along the neighbouring interfaces on peeling were examined leading to clear correlations between the observed morphology and mechanical peel strength data.