Laser-ablated Mo and W atoms react with CO in excess neon to give the same unsaturated M(CO)(3,4,5) carbonyls observed from photodissociation of M(CO)(6). The observed neon matrix fundamentals for these M(CO)(3,4,5) species bridge previous argon matrix and gas phase values. The M(CO)(2) dicarbonyls absorb at 1895.2 and 1884.5 cm(-1), and the MCO monocarbonyls absorb at 1881.2 and 1859.9 cm(-1) for Mo and W, respectively. The M(CO)1,2(+) cations and M(CO)(1.2)(-) anions are observed as the ablation process also provides cations and electrons. Density functional theory calculations support the product identifications and vibrational assignments.