Journal of Power Sources, Vol.114, No.1, 105-112, 2003
Hot-pressed, dry, composite, PEO-based electrolyte membranes I. Ionic conductivity characterization
Lithium polymer composite electrolytes, formed by a blend of poly(ethylene oxide) (PEO), LiCF3SO3 lithium salt and a selected, nanoparticle ceramic filler, were prepared by hot-pressing through a solvent-free procedure. These dry, ionically conducting membranes were characterized in terms of ionic conductivity in the 30-105 degreesC temperature range. The influences of several parameters such as the temperature, PEO molecular mass, the EO/Li molar ratio, and the nature and the content of ceramic filler were carefully evaluated.
Keywords:poly(ethylene oxide);dry polymer electrolyte;solvent-free preparation;hot-pressing;solid-state electrolytes;composite electrolytes;conductivity