Chemical Engineering Journal, Vol.92, No.1-3, 151-159, 2003
The application of fine TiO2 particles for enhanced gas absorption
The physical absorption of pure CO, in various liquids (water, hexadecane, and sunflower oil) containing micron sized TiO2 particles has been investigated. Absorption studies were carried out in a batch stirred cell reactor at 298 K and initial pressures of 0.08 MPa. Solid loading and stirring intensities were varied systematically between 0-15 kg/m(3) and 3.3-12.5 s(-1), respectively. Gas absorption rates are enhanced significantly in the presence of TiO2, particles. Enhancement factors are a function of the solids loading and stirring intensity. Maximum enhancement factors of about 2 were observed for all solvents at low stirring intensities. The rate of gas absorption was theoretically analyzed using a heterogeneous unsteady state mass transfer model based on the Danckwerts surface renewal theory and a Langmuir-type of particle to interface adhesion isotherm. This model not only predicts the trends in the observed enhancement factors very well but also gives an accurate quantitative picture.
Keywords:enhanced gas absorption;TiO2 particles;stirred cell reactor;surface renewal model;particle to interface adhesion isotherm