Journal of Applied Polymer Science, Vol.89, No.4, 1132-1138, 2003
Rheological behavior of ethylene-octene copolymer vulcanizates: Effect of blowing agent and precipitated silica filler
An experimental study of the rheological behavior of ethylene-octene copolymer vulcanizates in extrusion containing blowing agent has been carried out. The cell morphology development has been studied through a scanning electron microscope. Rheological properties of unfilled and precipitated silica-filled systems with variations of blowing agent, extrusion temperature, and shear rate have been studied by using a Monsanto processibility tester (MPT). The total extrusion pressure (P-T), apparent shear stress (tau(wa)), apparent viscosity (eta(a)), and die swell (%) of the unfilled and silica-filled compounds have been determined by using MPT. The effect of blowing agent (ADC) on the rheological properties of the vulcanizates has also been investigated. There is a reduction of stress and viscosity with blowing agent loading. It was observed that the incorporation of a blowing agent led to decreased shear thinning behavior resulting in an increase in power law index. The viscosity reduction factor (VRF) of unfilled vulcanizates is found to be dependent on the concentration of the blowing agent, shear rate, and temperature, whereas VRF of silicafilled vulcanizates is found to be dependent on shear rate, temperature, and blowing agent concentration. (C) 2003 Wiley Periodicals, Inc.