Journal of Chemical Physics, Vol.118, No.23, 10431-10438, 2003
New rovibrational kinetic energy operators using polyspherical coordinates for polyatomic molecules
We illustrate how one can easily derive kinetic energy operators for polyatomic molecules using polyspherical coordinates with very general choices for z- axis embeddings and angles used to specify relative orientations of internal vectors. Computer algebra is not required. (C) 2003 American Institute of Physics.