Journal of Polymer Science Part B: Polymer Physics, Vol.41, No.12, 1362-1374, 2003
Protrusion and deformation of an elastic particle at an advancing front interface
The response of an elastic particle to an extensional field close to an advancing liquid-gas interface in a capillary was examined both from an experimental and theoretical viewpoint. Experimental evidence is given on both the protrusion and deformation of an elastic particle at an advancing front interface. To interpret our experimental results, we followed and extended Hoffman's approach to the case of deformable particles. A hybrid approach was followed where the height of the bump was calculated theoretically as an equilibrium between capillary and drag forces for a given deformation of the particle, whereas the latter was supplied by an independent experimental measurement. For an elastic particle, the height of the bump goes through a maximum and further on decay almost linearly when plotted against the dimensionless parameter introduced by Hoffman. The difference between the theoretical prediction and the experimental data is discussed in relation to the asymmetry of the bump profiles observed in the experiment that could be responsible for a larger contribution of capillary forces from those calculated. (C) 2003 Wiley Periodicals, Inc.