Preparation and Dental Properties of Polymeric Dental Restorative Composites Using Oligoethyleneglycol Diluent System

Ohyoung Kim; Myung-Seon Gong

Journal of Industrial and Engineering Chemistry, Vol.9, No.3, 233-242, May, 2003

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Preparation and Dental Properties of Polymeric Dental Restorative Composites Using Oligoethyleneglycol Diluent System

Ohyoung Kim^†, and Myung-Seon Gong¹

Department of Polymer Science & Engineering, Dankook University, Seoul 140-714, Korea
¹Department of Chemistry, Dankook University, Cheonam, Chungnam 330-714, Korea

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The preparation of polymeric dental restorative composites (PDRC) was carried out using barium silicate filler and bisphenol-A glycerolate dimethacrylate resin matrix diluted with diacrylates or divinylethers of oligoethyleneglycols. Visible light was utilized to activate the resin matrix for polymerization. In order to enhance the miscibility of inorganic filler with organic resin matrix in PDRC and to conduct the homogeneity of filler, its surface was hydrophobically treated with γ-methacryloxypropyltrimethoxysilane and freeze-drying method was adopted to remove the solvents. Diametral tensile strength, flexural strength, degree of conversion, depth of cure, polymerization shrinkage, wear resistance, and surface characteristics were investigated to study the effect of diluents onto the dental properties of PDRC prepared herein.

Keywords:dental;restorative;diacrylate;divinylether;diluent

[References]

Bowen RL, U.S. Patent, 3,066,122 (1962)
Bowen RL, U.S. Patent, 3,179,523 (1965)
Bowen RL, J. Am. Dent. Assoc., 66, 57 (1963)
Bowen RL, J. Am. Dent. Assoc., 69, 481 (1964)
Williams DF, "Materials Science and Technology," Vol. 14, VCH, 209 (1992)
Kim SW, Jang JS, Polym. Eng. Sci., 38(7), 1142 (1998)
Pentzfeldt A, Eur. J. Oral Sci., 105, 97 (1997)
Ruyter IE, "Posterior Composite Resin Dental REstorative Materials," Eds. by G. Vanherle and D.S. Smith, Peter Szule Pub. Co., The Netherlands, 109 (1985)
Byerley TJ, Eick JD, Chen GP, Chappelow CC, Millich F, Dent. Mater., 8, 345 (1992)
Kim O, Shim WJ, Polym. Compos., 22(5), 650 (2001)
Kim O, Lee T, J. Ind. Eng. Chem., 7(2), 78 (2001)
Heigl JJ, Bell MF, White JU, Anal. Chem., 19(5), 293 (1947)
Ruyter IE, Svendsen SA, Acta Odontol. Scand., 36, 75 (1978)
Ishida H, Kumar G, "Molecular Characterization of Composite Interfaces," Plenum Press, New York (1985)
McCabe JE, Carrick TE, J. Dent. Res., 68, 1537 (1989)
Kim SW, Ph.D. Dissertation, Seoul Nat'l Univ., Seoul, Korea (1999)
Counsil on Dental Materials, Instruments and Equipment, American Dental Association Spec. No. 27 for Resin-Based Filling Materials (1993)
Dentistry-Synthetic Polymer Teeth, ISO Spec. No. 3336 (1993)
Kim O, J. Korean Ind. Eng. Chem., 11(6), 651 (2000)
Kim O, J. Korean Ind. Eng. Chem., 14(3), 313 (2003)
Stansbury JW, Dickens SH, Dent. Mater., 17, 71 (2001)
Cowperthwatte GF, Foy JJ, Malloy MA, Biomedical and Dental Applications of Polymers, Eds. by C.G. Gebelein and F.F. Koblitz, Plenum Press, New York, 379 (1981)
Moore JE, Am. Chem. Soc. Coatings Plast. Prepr., 36, 747 (1976)
Atmadja G, Bryant RW, Aust. Dent. J., 35, 213 (1990)
Dentistry-Resin Based Filling Materials, ISO Spec. No. 4049 (1978)
McMurry J, Fundamentals of Organic Chemistry, Brooks/Cole Pub. Co., Monterey, CA (1986)
Cook WD, Forrest M, Goodwin AA, Dent. Mater., 15, 447 (1999)
Goldman M, Aust. Dent. J., 28, 156 (1983)
Asmussen E, Pentzfeldt A, Dent. Mater., 14, 51 (1998)
Ferracane JL, Mitchem JC, Condon JR, Todd R, J. Dent. Res., 76, 1508 (1997)
Pentzfeldt A, Asmussen E, J. Dent. Res., 71, 1847 (1992)
Venhoven BMA, deGee AJ, Werner A, Davidson CL, Biomaterials, 17, 735 (1996)
Soderholm KJM, Richard ND, Gen. Dent., 46, 256 (1998)
Mair LH, Stolarski TA, Vowles RW, Lloyd CH, J. Dent., 24, 141 (1996)
Lim BS, Ferraccane JL, Condon JR, Adey JD, Dent. Mater., 18, 1 (2002)

[Referenced By]

[Related Articles]

[1] Bowen RL, U.S. Patent, 3,066,122 (1962)

[2] Bowen RL, U.S. Patent, 3,179,523 (1965)

[3] Bowen RL, J. Am. Dent. Assoc., 66, 57 (1963)

[4] Bowen RL, J. Am. Dent. Assoc., 69, 481 (1964)

[5] Williams DF, "Materials Science and Technology," Vol. 14, VCH, 209 (1992)

[6] Kim SW, Jang JS, Polym. Eng. Sci., 38(7), 1142 (1998)

[7] Pentzfeldt A, Eur. J. Oral Sci., 105, 97 (1997)

[8] Ruyter IE, "Posterior Composite Resin Dental REstorative Materials," Eds. by G. Vanherle and D.S. Smith, Peter Szule Pub. Co., The Netherlands, 109 (1985)

[9] Byerley TJ, Eick JD, Chen GP, Chappelow CC, Millich F, Dent. Mater., 8, 345 (1992)

[10] Kim O, Shim WJ, Polym. Compos., 22(5), 650 (2001)

[11] Kim O, Lee T, J. Ind. Eng. Chem., 7(2), 78 (2001)

[12] Heigl JJ, Bell MF, White JU, Anal. Chem., 19(5), 293 (1947)

[13] Ruyter IE, Svendsen SA, Acta Odontol. Scand., 36, 75 (1978)

[14] Ishida H, Kumar G, "Molecular Characterization of Composite Interfaces," Plenum Press, New York (1985)

[15] McCabe JE, Carrick TE, J. Dent. Res., 68, 1537 (1989)

[16] Kim SW, Ph.D. Dissertation, Seoul Nat'l Univ., Seoul, Korea (1999)

[17] Counsil on Dental Materials, Instruments and Equipment, American Dental Association Spec. No. 27 for Resin-Based Filling Materials (1993)

[18] Dentistry-Synthetic Polymer Teeth, ISO Spec. No. 3336 (1993)

[19] Kim O, J. Korean Ind. Eng. Chem., 11(6), 651 (2000)

[20] Kim O, J. Korean Ind. Eng. Chem., 14(3), 313 (2003)

[21] Stansbury JW, Dickens SH, Dent. Mater., 17, 71 (2001)

[22] Cowperthwatte GF, Foy JJ, Malloy MA, Biomedical and Dental Applications of Polymers, Eds. by C.G. Gebelein and F.F. Koblitz, Plenum Press, New York, 379 (1981)

[23] Moore JE, Am. Chem. Soc. Coatings Plast. Prepr., 36, 747 (1976)

[24] Atmadja G, Bryant RW, Aust. Dent. J., 35, 213 (1990)

[25] Dentistry-Resin Based Filling Materials, ISO Spec. No. 4049 (1978)

[26] McMurry J, Fundamentals of Organic Chemistry, Brooks/Cole Pub. Co., Monterey, CA (1986)

[27] Cook WD, Forrest M, Goodwin AA, Dent. Mater., 15, 447 (1999)

[28] Goldman M, Aust. Dent. J., 28, 156 (1983)

[29] Asmussen E, Pentzfeldt A, Dent. Mater., 14, 51 (1998)

[30] Ferracane JL, Mitchem JC, Condon JR, Todd R, J. Dent. Res., 76, 1508 (1997)

[31] Pentzfeldt A, Asmussen E, J. Dent. Res., 71, 1847 (1992)

[32] Venhoven BMA, deGee AJ, Werner A, Davidson CL, Biomaterials, 17, 735 (1996)

[33] Soderholm KJM, Richard ND, Gen. Dent., 46, 256 (1998)

[34] Mair LH, Stolarski TA, Vowles RW, Lloyd CH, J. Dent., 24, 141 (1996)

[35] Lim BS, Ferraccane JL, Condon JR, Adey JD, Dent. Mater., 18, 1 (2002)