- Previous Article
- Next Article
- Table of Contents
Korea-Australia Rheology Journal, Vol.15, No.2, 97-105, June, 2003
Nonlinear response of complex fluids under LAOS (large amplitude oscillatory shear) flow
E-mail:
In the previous paper (Hyun et al., 2002), we have investigated the shape of storage modulus (G’) and loss modulus (G”) of complex fluids under large amplitude oscillatory shear (LAOS) flow. As the strain amplitude increases, however, the stress curve becomes distorted and some important information may be smothered during data processing. Thus we need to investigate the stress data more precisely and systematically. In this work, we have obtained the stress data using high performance ADC (analog digital converting) card, and investigated the nonlinear response of complex fluids, 4wt% xanthan gum (XG), 2 wt% PVA/ 1 wt% Borax, and 1 wt% hyaluronic acid (HA) solutions, using Fourier transformation (FT) rheology. Comparing the strain signals in time domain with FT parameters in frequency domain, we could illustrate the sensitivity and importance of FT rheology. Diverse and unique stress patterns were observed depending on the material system as well as flow environment. It was found that they are not the outcome of experimental deficiency like wall slip but characteristics of the material system. When nonlinear response of complex fluids is analyzed, the intensity and phase angle of higher harmonic contributions should be considered together, and the shape of the stress signal was found to be strongly dependent upon phase angle.
-
Daniel C, Hamley IW, Wilhelm M, Mingvanish W, Rheol. Acta, 40(1), 39 (2001)
- Dealy JM, Wissbrun KF, Melt Rheology and Its Rolein Plastics Processing: Theory and Applications, VNR, New York, Chapter 5 (1990)
- Giacomine AJ, Dealy JM, Large-Amplitude Oscillatory Shear, in : Collyer, A.A. (Ed.), Techniques in Rheological Measurement, Chapman & Hall, London, Chapter 4 (1993)
-
Graham MD, J. Rheol., 39(4), 697 (1995)
-
Hyun K, Kim SH, Ahn KH, Lee SJ, J. Non-Newton. Fluid Mech., 107(1-3), 51 (2002)
- Inoue T, Osaki K, Rheol. Acta, 32, 550 (1993)
- Kim SH, Sim HG, Ahn KH, Lee SJ, Korea-Aust. Rheol. J., 14(2), 49 (2002)
- Larson RG, The Structure and Rheology of Complex Fluids, Oxford University Press, New York (1999)
- Laurent TC, Fraser JRE, Hyaluronan, FASEB J., 6, 2397 (1992)
- Neidhofer T, Wilhelm M, Debbaut B, Hadjichristidis N, FT-rheology and Finite-Element Simulations on Polystyrene Solutions and Melts of Various Topologies, Proceedings of the 6th European Conference on Rheology, 463-464 (2002)
- Onogi S, Masuda T, Matsumoto T, Trans. Soc. Rheol., 14, 275 (1970)
-
Reimers MJ, Dealy JM, J. Rheol., 40(1), 167 (1996)
- Rochefort WE, Middleman S, J. Rheol., 31, 337 (1987)
- Sim HG, Ahn KH, Lee SJ, J. Non-Newton. Fluid Mech., accepted (2003)
- Skoog DA, Leary JJ, Principles of Instrumental Analysis, Sauders College Publishing, Fort Worth (1992)
-
van Dusschoten D, Wilhelm M, Rheol. Acta, 40(4), 395 (2001)
-
Wilhelm M, Maring D, Spiess HW, Rheol. Acta, 37(4), 399 (1998)
-
Wilhelm M, Reinheimer P, Ortseifer M, Rheol. Acta, 38(4), 349 (1999)
-
Wilhelm M, Reinheimer P, Ortseifer M, Neidhofer T, Spiess HW, Rheol. Acta, 39(3), 241 (2000)
- Wilhelm M, Macromol. Mater. Eng., 287, 83 (2002)
-
Yosick JA, Giacomin AJ, Moldenaers P, J. Non-Newton. Fluid Mech., 70(1-2), 103 (1997)