화학공학소재연구정보센터
Rheologica Acta, Vol.42, No.3, 199-208, 2003
Dynamic properties of shear thickening colloidal suspensions
The transient shear rheology (i.e., frequency and strain dependence) is compared to the steady rheology for a model colloidal dispersion through the shear thickening transition. Reversible shear thickening is observed and the transition stress compares well to theoretical predictions. Steady and transient shear thickening are observed to occur at the same value of the average stress. The critical strain for shear thickening is found to depend inversely on the frequency at fixed applied stress for low frequencies (high strains), but is limited to an apparent minimum critical strain at higher frequencies. This minimum critical strain is shown to be an artifact of slip. Lissajous plots illustrate the transition in material properties through the shear thickening transition, and the energy dissipated by a shear thickening suspension is analyzed as a function of strain amplitude.