화학공학소재연구정보센터
Macromolecular Research, Vol.11, No.4, 224-230, August, 2003
Structure -Properties Relations of Polypropylene/ Liquid Crystalline Polymer Blends
E-mail:
The blends of polypropylene (PP) with glass filled thermotropic liquid crystalline polymer (LCP-g) have been prepared by melt mixing techniques at different blend ratios. The thermal, dynamic mechanical, crystalline and morphological characteristics of these blends were investigated. Higher percent crystallinity was observed for 10% level of LCP-g in the blend in comparison to that of other blend ratios. The thermal stability increased with LCP-g concentration in the blend with PP. The variation of storage modulus, stiffness and loss modulus as a function of blend ratios suggested the phase inversion at the 50% level of LCP-g in the blend. The scanning electron microscopy (SEM) photographs showed the creation of voids and destruction of the fiber structures during the dynamic mechanical measurements. Processing behavior of the blends depended on the fiber forming characteristics of LCP-g, which again varied with the molding temperatures.
  1. Paul DR, Newman S, Polymer Blends, Academic Press, New York, vol. 1&2 (1978)
  2. Beers DE, Ramirez JE, J. Text. Inst., 81, 561 (1990)
  3. Blonski S, Brostow W, J. Chem. Phys., 95, 2890 (1991) 
  4. Golovoy A, Kozlowski M, Narkis M, Polym. Eng. Sci., 32, 854 (1992) 
  5. Bassett BR, Yee AF, Polym. Compos., 11, 10 (1990) 
  6. LaMantia FP, Magagnini PL, Pedretti U, Polym. Networks & Blends, 2, 41 (1992)
  7. Hong SM, Kim BC, Kim KU, Chung IJ, Polym. J., 23, 1347 (1991) 
  8. Amendola E, Carfagna C, Netti P, Nicolais L, Saiello S, J. Appl. Polym. Sci., 50, 83 (1993) 
  9. Joslin S, Jackson W, Farris R, J. Appl. Polym. Sci., 54(4), 439 (1994) 
  10. Tjong SC, Liu SL, Li RK, J. Mater. Sci., 30(2), 353 (1995) 
  11. Datta A, Baird DG, Polymer, 36(3), 505 (1995) 
  12. Heino MT, Seppala JV, Polym. Bull., 30, 353 (1993) 
  13. Bualek-Limcharoen S, Samran J, Amornsakchai T, Meesiri W, Polym. Eng. Sci., 39(2), 312 (1999) 
  14. Seppala J, Heino M, Kapanen C, J. Appl. Polym. Sci., 44, 1051 (1992) 
  15. Heino MT, Hietaoja PT, Vainio TP, Seppala JV, J. Appl. Polym. Sci., 51(2), 259 (1994) 
  16. Alexander LE, Polymer Science, Wiley Interscience, New York (1969)
  17. Roychowdhury S, Das CK, Polym. Polym. Compos., 8(3), 177 (2000)
  18. Ha CS, Kim SC, J. Appl. Polym. Sci., 35, 2211 (1988) 
  19. Weinkauf DH, Paul DR, J. Polym. Sci. B: Polym. Phys., 30, 837 (1992) 
  20. Gomes M, Scuccuglia M, Bretas RES, J. Mater. Sci., 34(6), 1407 (1999) 
  21. Takayanagi M, Viscoelastic Properties of Crystalline Polymers, Memorandum of the Faculty of Engineering, Kyushu University, Vol. 23, No. 1
  22. Jang GS, Cho WJ, Ha CS, J. Polym. Sci. B: Polym. Phys., 39(10), 1001 (2001) 
  23. Jang GS, Cho WJ, Ha CS, Kim W, Kim HK, Colloid Polym. Sci., 280, 424 (2002)