Journal of Chemical Physics, Vol.119, No.5, 2812-2819, 2003
Dielectric permittivity and electric modulus in Bi2Ti4O11
Frequency and temperature dependences of dielectric permittivity and electric modulus of pure and Ba-doped Bi2Ti4O11 were studied in the ranges of 10(-1)-10(6) Hz and -150-350 degreesC, respectively. We found that the antiferroelectric phase transition temperature of Bi2Ti4O11 decreases with Ba doping. In the permittivity studies, we also observed dielectric relaxation peaks shift to higher temperature with increasing frequency. Furthermore, in the electric modulus formalism, conducting peaks were uncovered above 150 degreesC in addition to the dielectric relaxation peak. We discussed the mechanisms for the dielectric relaxation and conduction processes based on TiO6 octahedra distortion and a space-charge model. (C) 2003 American Institute of Physics.