Chiral Schiff Base Ruthenium(III) Complexes: Synthesis, Characterisation, Catalytic and Antibacterial Studies

T. Daniel Thangadurai; Son-Ki Ihm

Journal of Industrial and Engineering Chemistry, Vol.9, No.5, 563-568, September, 2003

Export Citation

Chiral Schiff Base Ruthenium(III) Complexes: Synthesis, Characterisation, Catalytic and Antibacterial Studies

T. Daniel Thangadurai, and Son-Ki Ihm^†

Department of Chemical and Biomolecular Engineering, Korea, Advanced Institute of Science and Technology, Daejeon 305-701, Korea

E-mail:

Chiral Schiff base ruthenium (III) complexes of the type [RuX(LL')(EPh₃)] (X = Cl or Br; LL' = chiral Schiff base; E = P or As) have been synthesised by the reactions of [RuX₃(EPh₃)₃] or [RuBr₃(PPh₃)2 (MeOH)] with appropriate Schiff bases having the donor groups (O,N) viz., bis[3(1'-naphthyl)salicylidenecy clohexanediimine](L1)orbis[3(1'-naphthyl)salicylidenepropylenediimine] (L2) or bis[3(1'-naphthyl)salicyliden ediphenyldiimine] (U) in 1: 1 molar ratio. The characterisation of the complex was done by elemental analyses and spectral (IR, UV-visible and EPR), electrochemical and magnetic moment data. An octahedral structure has been tentatively proposed for all the new complexes. The catalytic and antibacterial activities have also been carried out for these new complexes.

Keywords:ruthenium (III);chiral schiff base;aerial oxidation;steric effect;tweedy's theory

[References]

Horowitz CP, Creager SE, Murray RW, Inorg. Chem., 29, 1006 (1990)
Gomes MD, Antunes OA, Catal. Lett., 38(1-2), 133 (1996)
Duprilot JM, Bediouni F, Devynck J, Folest JC, Bied-Charreton C, J. Org. Chem., 286, 77 (1985)
Dahm CE, Peters DG, Anal. Chem., 66, 3117 (1994)
Szlyk E, Biniak S, Surdykowski A, Lakomska I, Magdalena M, Larsen E, Trans. Met. Chem., 27, 501 (2002)
Downing RS, Urbach FL, J. Am. Chem. Soc., 91, 5977 (1969)
Kuresky RI, Khan NH, Abdi SHR, Bhatt AK, J. Mol. Catal., 110, 33 (1996)
Kuresky RI, Khan NH, Abdi SHR, J. Mol. Catal., 96, 117 (1995)
Kuresky RI, Khan NH, Abdi SHR, Iyer P, Bhatt AK, J. Mol. Catal., 120, 101 (1997)
Csjernyik G, Ell AH, Fadini L, Pugin B, Backvall JE, J. Org. Chem., 67, 1657 (2002)
Taqui Khan MM, Halligudy SB, Shaikh ZA, J. Mol. Catal., 57, 301 (1990)
Lee JD, Lee MH, J. Ind. Eng. Chem., 7(3), 137 (2001)
Choi WJ, Park JY, Kim MS, Park HS, Hahm HS, J. Ind. Eng. Chem., 7(4), 187 (2001)
Kuresky RI, Khan NH, Abdi SHR, J. Mol. Catal., 96, 117 (1995)
Kim CH, Choi KS, J. Ind. Eng. Chem., 8(1), 71 (2002)
Vogel AI, Textbook of Practical Organic Chemistry, Longman, Londan (1989)
Ahamed W, Levision JJ, Robinson SD, Hely M, Inorganic. Syntheses, G.W. Parshall Ed., Vol. XV, p. 48, McGraw-Hill, New York (1974)
Kuresky RI, Khan NH, Abdi SHR, Iyer P, Bhatt AK, J. Mol. Catal., 120, 25 (1997)
Thangadurai TD, Natarajan K, Trans. Met. Chem., 26, 717 (2001)
Thangadurai TD, Natarajan K, Synth. React. Inorg. Met. Org. Chem., 31, 549 (2001)
Ramesh R, Dharmaraj N, Karvembu R, Natarajan K, Ind. J. Chem., 39A, 1079 (2000)
Lever ABP, Inorganic Electronic Spectroscopy, Elsevier, New York (1984)
Shirin Z, Mukherjee RN, Polyhedron, 11, 2625 (1992)
Thangadurai TD, Natarajan K, Ind. J. Chem., 40A, 573 (2001)
Ramesh R, Suganthy PK, Synth. React. Inorg. Met. Org. Chem., 26, 47 (1996)
Khan MMT, Kuresky RI, Khan NH, Polyhedron, 1, 2559 (1991)
Orabi AS, Ayad MI, Ramadan AEM, Trans. Met. Chem., 23, 889 (1995)
Sreekala R, MohammedYusuff KK,, Ind. J. Chem., 34A, 994 (1995)
Saran NK, Dash MN, Acharya RC, Ind. J. Chem., 18A, 994 (1979)
Tweedy BG, Phytopathology, 55, 910 (1964)
Maruvada R, Pal SC, Balakrishnair G, J. Micro. Bio. Methods, 20, 115 (1994)
Franklin TJ, Snow GA, Penetrating the Defences. In Biochemistry of Antimicrobial Action, 2nd Edn., Chapman and Hall, London (1971)
Singh SC, Gupta N, Singh RV, Int. J. Chem., 38A, 797 (1999)
Lawrence PG, Harold PL, Francis OG, Antibio. Chemther., 1597 (1980)

[Referenced By]

[Related Articles]

[1] Horowitz CP, Creager SE, Murray RW, Inorg. Chem., 29, 1006 (1990)

[2] Gomes MD, Antunes OA, Catal. Lett., 38(1-2), 133 (1996)

[3] Duprilot JM, Bediouni F, Devynck J, Folest JC, Bied-Charreton C, J. Org. Chem., 286, 77 (1985)

[4] Dahm CE, Peters DG, Anal. Chem., 66, 3117 (1994)

[5] Szlyk E, Biniak S, Surdykowski A, Lakomska I, Magdalena M, Larsen E, Trans. Met. Chem., 27, 501 (2002)

[6] Downing RS, Urbach FL, J. Am. Chem. Soc., 91, 5977 (1969)

[7] Kuresky RI, Khan NH, Abdi SHR, Bhatt AK, J. Mol. Catal., 110, 33 (1996)

[8] Kuresky RI, Khan NH, Abdi SHR, J. Mol. Catal., 96, 117 (1995)

[9] Kuresky RI, Khan NH, Abdi SHR, Iyer P, Bhatt AK, J. Mol. Catal., 120, 101 (1997)

[10] Csjernyik G, Ell AH, Fadini L, Pugin B, Backvall JE, J. Org. Chem., 67, 1657 (2002)

[11] Taqui Khan MM, Halligudy SB, Shaikh ZA, J. Mol. Catal., 57, 301 (1990)

[12] Lee JD, Lee MH, J. Ind. Eng. Chem., 7(3), 137 (2001)

[13] Choi WJ, Park JY, Kim MS, Park HS, Hahm HS, J. Ind. Eng. Chem., 7(4), 187 (2001)

[14] Kuresky RI, Khan NH, Abdi SHR, J. Mol. Catal., 96, 117 (1995)

[15] Kim CH, Choi KS, J. Ind. Eng. Chem., 8(1), 71 (2002)

[16] Vogel AI, Textbook of Practical Organic Chemistry, Longman, Londan (1989)

[17] Ahamed W, Levision JJ, Robinson SD, Hely M, Inorganic. Syntheses, G.W. Parshall Ed., Vol. XV, p. 48, McGraw-Hill, New York (1974)

[18] Kuresky RI, Khan NH, Abdi SHR, Iyer P, Bhatt AK, J. Mol. Catal., 120, 25 (1997)

[19] Thangadurai TD, Natarajan K, Trans. Met. Chem., 26, 717 (2001)

[20] Thangadurai TD, Natarajan K, Synth. React. Inorg. Met. Org. Chem., 31, 549 (2001)

[21] Ramesh R, Dharmaraj N, Karvembu R, Natarajan K, Ind. J. Chem., 39A, 1079 (2000)

[22] Lever ABP, Inorganic Electronic Spectroscopy, Elsevier, New York (1984)

[23] Shirin Z, Mukherjee RN, Polyhedron, 11, 2625 (1992)

[24] Thangadurai TD, Natarajan K, Ind. J. Chem., 40A, 573 (2001)

[25] Ramesh R, Suganthy PK, Synth. React. Inorg. Met. Org. Chem., 26, 47 (1996)

[26] Khan MMT, Kuresky RI, Khan NH, Polyhedron, 1, 2559 (1991)

[27] Orabi AS, Ayad MI, Ramadan AEM, Trans. Met. Chem., 23, 889 (1995)

[28] Sreekala R, MohammedYusuff KK,, Ind. J. Chem., 34A, 994 (1995)

[29] Saran NK, Dash MN, Acharya RC, Ind. J. Chem., 18A, 994 (1979)

[30] Tweedy BG, Phytopathology, 55, 910 (1964)

[31] Maruvada R, Pal SC, Balakrishnair G, J. Micro. Bio. Methods, 20, 115 (1994)

[32] Franklin TJ, Snow GA, Penetrating the Defences. In Biochemistry of Antimicrobial Action, 2nd Edn., Chapman and Hall, London (1971)

[33] Singh SC, Gupta N, Singh RV, Int. J. Chem., 38A, 797 (1999)

[34] Lawrence PG, Harold PL, Francis OG, Antibio. Chemther., 1597 (1980)