Applied Chemistry, Vol.7, No.2, 475-478, October, 2003
방사선에 의한 폴리아닐린/은 복합제의 제조 및 전기전도 특성
Preparation and Electrical Conducting Properties of Polyaniline/Silver Composite by γ-irradiation
The conducting Ag/PANI composites were prepared by 60Co γ-irradiation using aniline monomer, hydrochloric acid and sulfuric acid as dopant, and AgCl2 for nano-sized Ag particle. And the effect of experimental conditions such as species and concentrations of dopants, and Ag/PANI mole ratio on the electrical conductivity was studied. Also, we investigated the electrical conductivity according to the absorbed dose of Ag/PANI compoistes. It showed that electrical conductivity of Ag/PANI composites. It showed that electrical conductivity of Ag/PANI composite was increased with the increase of the Ag/PANI mole ratio and concentration of popant in case that H2SO4 was used as dopant. On the other hand, electrical conductivity showed maximum value and decreased with the increase of the Ag/PANI mole ratio and concentration of dopant in case of HCl dopant. The electrical conductivity of γ-ray irradiated Ag/PANI was increased up to 30kGy irradiation and decreased above 30kGy.