화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of the Korean Industrial and Engineering Chemistry, Vol.14, No.8, 1154-1158, December, 2003
Export Citation
전분/펙틴/몬모릴로나이트 나노복합 필름의 특성 및 산소 투과도 연구
A Study on the Property and Oxygen Permeability of Starch/Pectin/Montmorillonite Nanocomposite
서석훈, 서길수, 유성구, 신용섭, 정세환, 김성철, 배광수1, 이태진, 장상희2, 신부영†
  • 영남대학교 응용화학공학과, 경산 712-749
  • 1안동정보대학 보건위생과, 안동 760-830
  • 2구미1대학 식품과학과, 구미 730-711
Suk Hun Sur, Gil Soo Sur, Sung Gyu Lyu, Yon Sub Shin, Se-Hwan Jung, Sung Choul Kim, Kwang Soo Bae1, Tae Jin Lee, Sang Hee Jang2, and Boo Young Shin†
  • Department of Chemical Engineering & Technology, Yeungnam University, 214-1 Dae-Dong, Gyeongsan 712-749, Korea
  • 1Department of Health and Hyginene Education, Andong Institute of Information and Technology, Andong 760-830, Korea
  • 2Department of Food Science, Gumi College, 407 Bugok-Dong , Gumi 730-711, Korea
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초록
Na+-MMT로부터 제조한 생분해성 전분/펙틴/몬모릴로나이트 나노복합재료의 기계적 특성, 열적 특성, 그리고 산소 투과성을 연구하였다. XRD와 TEM의 결과로부터 고분자의 삽입으로 인하여 실리케이트 층간 간격이 증가하였으며, 또한 삽입형 전분/펙틴/몬모릴로나이트 나노복합재료임을 확인하였다. 합성된 전분/펙틴/몬모릴로나이트 나노복합재료의 경우 적은 양의 MMT로부터 기계적 특성과 열적 안정성이 우수함을 보였다. 그리고 전분/펙틴/몬모릴로나이트 나노복합재료의 산소 투과성은 고분자 매트릭스에 분산되어 있는 몬모릴로나이트에 의하여 현저히 저하됨을 보여주었다.
Mechanical property, thermal property, and oxygen permeability of biodegradable Pectin/Starch-montmorillonite nanocomposite, prepared with Na+-MMT, have been studied. X-ray diffraction and TEM experiments on polymer/silicate composite samples demonstrated that the intercalation of polymer chains leads to increase in the spacing between silicate layers. In addition, it were found that the intercalated Starch/Pectin/montmorillonite nanocomposite were prepared. It was found that the addition of only a small amount of clay was enough to improve the thermal stability and mechanical property of Starch/Pectin/montmorillonite nanocomposite. Oxygen permeability of Starch/Pectin/montmorillonite composite was generally lower than that of pectin/starch.
Keywords:starch;pectin;montmorillonite;nanocomposite
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