This paper deals with the exergy analysis (EXA) of plaster materials and ranks the environmental burdens due to the production of such materials. The calculation of the exergy loss during the whole examined process represents a relevant index, looking at the technology improvement of a process, as a suitable tool in aid of the trade-off of alternative materials in the decision making. A life cycle inventory is performed for building plaster products and the matrix method is used. The authors extend the application of EXA to life cycle assessment, conducting an,exergetic life cycle assessment, and propose an exergetic index in the framework of multi-criteria decision making., An exergy balance, accounting for energy and material flows, is applied to calculate the exergy losses and efficiencies for each stage of the examined processes: resources extraction, materials processing, transport and product manufacturing. Furthermore, exergy values are calculated for the pollutants and wastes. (C) 2003 Elsevier Science Ltd. All rights reserved.