Journal of Physical Chemistry A, Vol.107, No.38, 7561-7566, 2003
Electric polarization of dilute polar solutions: Revised treatment for arbitrary shaped molecules
A model for deducing dipole moments of solute molecules from the electric polarization of dilute solutions is revised. The treatment represents a modified Onsager model extended toward arbitrary-shaped molecules. A simplified approach for data evaluation is suggested and compared with the analytical solution for an ellipsoidal cavity and with a numerical solution for two spherical ions.