화학공학소재연구정보센터
Journal of Rheology, Vol.47, No.4, 1041-1050, 2003
Enhancement of the first normal stress coefficient and dynamic moduli during shear thickening of a polymer solution
Viscosity results of a solution of poly (2-hydroxyethyl methacrylamide) in glycerine, obtained from a continuous increase of shear rate and under steady state (constant shear rate) conditions, reveal the existence of a shear thickening region. The analysis of normal stresses shows that the first normal stress coefficient exhibits the same shear-thickening effect as the viscosity. The increase of the solution elasticity during shear thickening is also noticed by an enhancement of the storage modulus, measured in experiments using parallel superposition of oscillations on steady flows, as the shear stress is increased. Thermorheological simplicity, observed in dynamic measurements in absence of steady flow, is broken when shear stresses corresponding to the shear thickening region are applied. The results are explained by the presence of shear-induced hydrogen bonds, which provoke a reinforcement of the plateau modulus and an enlargement of the relaxation time spectrum. (C) 2003 The Society of Rheology.