화학공학소재연구정보센터
AIChE Journal, Vol.49, No.10, 2519-2532, 2003
Modeling adsorption of cane-sugar solution colorant in packed-bed ion exchangers
The removal of cane-sugar solution colorant by packed-bed ion exchangers was modeled using a linear driving-force adsorption model. Adsorption of colorant is a complex subject, since color is an indiscrete mixture of many components, making it difficult to measure and even more challenging to model. Three resins were investigated: a strong-acid cation (SAC), a weak-base anion (WBA), and a standard sugar industry strong-base anion decolorizing resin. Batch testing of the resins produced linear isotherms, indicating that the colorant is dilute. Results from column testing showed that a plug-flow model with a constant linear isotherm was sufficient in all cases except the SAC resin. The SAC adsorption parameter decreased sharply as the pH increased, causing the colorant to be desorbed from the resin. This situation must be avoided if optimal decolorization is to be achieved.