고밀도의 이산화탄소와 윤활유의 상호용해도 측정

배효광; 서정태

HWAHAK KONGHAK, Vol.37, No.3, 417-420, June, 1999

Export Citation

고밀도의 이산화탄소와 윤활유의 상호용해도 측정

Measurement of Mutual Solubility of Carbon Dioxide and Lubricating Oil at High Pressure

배효광, 서정태

초록

유통형인 고압기액평형측정 장치를 사용하여 고밀도상태의 이산화탄소와 윤활유분의 상호 용해도를 298.15K, 308.15K, 328.15 K와 343.15 K의 온도와 2 MPa에서 20 MPa 사이의 압력범위에서 측정하였다. 윤활유분을 순수한 단일성분으로 가정하고 평균분자량, 임계특성값을 Kesler-Lee의 상관관계식에 의하여 추정하고 상태방정식에 의한 기-액양상 중의 이산화탄소와 윤활유분의 상호용해도를 계산하여 계산값과 측정값을 비교하였으며 작은 편차로 잘 일치하였다.

The mutual solubility of carbon dioxide and lubricating oil was measured at the temperatures 298.15 K, 308.15 K, 328.15 K, 343.15 K and the pressure range between 2 MPa and 20 MPa, by using the flow-type apparatus for high pressure gas-liquid equilibrium. Supposing the lube oil fraction as a pure psudocomponent, the average molecular weight, critical properties and acentric factor were estimated by Kesler-Lee correlation. The solubilities of carbon dioxide in liquid phase and lube oil in gas phase were predicted by using an equation of state. The average absolute deviations between observed and calculated concentration of each phase were not great.

Keywords:Solubility;Carbon Dioxide;Lubricating Oil;High Pressure

[References]

Kesler MG, Lee BI, Hydrocarb. Process., March, 153 (1976)
Mehrotra AK, Svrcek WY, Can. J. Chem. Eng., 66, 656 (1988)
Hutchenson KW, Robers JR, Thies MC, J. Supercrit. Fluids, 4, 7 (1991)
Hutchenson KW, Robers JR, Thies MC, J. Supercrit. Fluids, 60, 309 (1990)
Hutchenson KW, Robers JR, Thies MC, Fluid Phase Equilib., 60, 309 (1990)
Radosz M, "Supercritical Fluid Technology," edited by Penninger, J.M.L. et al., Elsevier Sci. Pub., 179 (1985)
Yu JM, Huang SH, Radosz M, Fluid Phase Equilib., 53, 429 (1989)
Huang SH, Radosz M, Fluid Phase Equilib., 60, 81 (1990)
Jennings DW, Lee RJ, Teja AS, J. Chem. Eng. Data, 36, 303 (1991)
Jamaluddin AKM, Kalogerakis NE, Chakma A, Fluid Phase Equilib., 64, 33 (1991)
Martin JJ, Ind. Eng. Chem. Fundam., 18(2), 81 (1979)
Peng D, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
Suzuki T, Tsuge N, Nagahama K, Fluid Phase Equilib., 67, 213 (1991)
Suzuki K, Sue H, J. Chem. Eng. Data, 35, 63 (1990)
Lee DK, Park SD, Kim SH, Lee JY, Lee KH, Lee KS, HWAHAK KONGHAK, 30(6), 681 (1992)
Nagahama K, J. Jpn. Petrol. Inst., 27, 506 (1984)
Nagahama K, J. Jpn. Petrol. Inst., 82, 63 (1985)
Bae HK, Lee JY, HWAHAK KONGHAK, 36(4), 584 (1998)
American Petroleum Institute: "Technical Data Book-Petroleum efining," 3rd Ed., 2B2.1, 2B2.2, 1976 (1976)
Lee SY, Kim SY, Yoo KP, Korean J. Chem. Eng., 10(1), 10 (1993)
Park J, Kim H, Korean J. Chem. Eng., 10(2), 71 (1993)
Willman B, Teja AS, Ind. Eng. Chem. Res., 26, 948 (1987)
Cotterman RL, Prausnitz JM, Ind. Eng. Chem. Process Des. Dev., 24, 434 (1985)

[1] Kesler MG, Lee BI, Hydrocarb. Process., March, 153 (1976)

[2] Mehrotra AK, Svrcek WY, Can. J. Chem. Eng., 66, 656 (1988)

[3] Hutchenson KW, Robers JR, Thies MC, J. Supercrit. Fluids, 4, 7 (1991)

[4] Hutchenson KW, Robers JR, Thies MC, J. Supercrit. Fluids, 60, 309 (1990)

[5] Hutchenson KW, Robers JR, Thies MC, Fluid Phase Equilib., 60, 309 (1990)

[6] Radosz M, "Supercritical Fluid Technology," edited by Penninger, J.M.L. et al., Elsevier Sci. Pub., 179 (1985)

[7] Yu JM, Huang SH, Radosz M, Fluid Phase Equilib., 53, 429 (1989)

[8] Huang SH, Radosz M, Fluid Phase Equilib., 60, 81 (1990)

[9] Jennings DW, Lee RJ, Teja AS, J. Chem. Eng. Data, 36, 303 (1991)

[10] Jamaluddin AKM, Kalogerakis NE, Chakma A, Fluid Phase Equilib., 64, 33 (1991)

[11] Martin JJ, Ind. Eng. Chem. Fundam., 18(2), 81 (1979)

[12] Peng D, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)

[13] Suzuki T, Tsuge N, Nagahama K, Fluid Phase Equilib., 67, 213 (1991)

[14] Suzuki K, Sue H, J. Chem. Eng. Data, 35, 63 (1990)

[15] Lee DK, Park SD, Kim SH, Lee JY, Lee KH, Lee KS, HWAHAK KONGHAK, 30(6), 681 (1992)

[16] Nagahama K, J. Jpn. Petrol. Inst., 27, 506 (1984)

[17] Nagahama K, J. Jpn. Petrol. Inst., 82, 63 (1985)

[18] Bae HK, Lee JY, HWAHAK KONGHAK, 36(4), 584 (1998)

[19] American Petroleum Institute: "Technical Data Book-Petroleum efining," 3rd Ed., 2B2.1, 2B2.2, 1976 (1976)

[20] Lee SY, Kim SY, Yoo KP, Korean J. Chem. Eng., 10(1), 10 (1993)

[21] Park J, Kim H, Korean J. Chem. Eng., 10(2), 71 (1993)

[22] Willman B, Teja AS, Ind. Eng. Chem. Res., 26, 948 (1987)

[23] Cotterman RL, Prausnitz JM, Ind. Eng. Chem. Process Des. Dev., 24, 434 (1985)