Density Correlation of Solubility of C. I. Disperse Orange 30 Dye in Supercritical Carbon Dioxide

Jong-Kook Baek; Sunwook Kim; Gwang-Soo Lee; Jae-Jin Shim

Korean Journal of Chemical Engineering, Vol.21, No.1, 230-235, January, 2004

DOI10.1007/BF02705403 Export Citation

Density Correlation of Solubility of C. I. Disperse Orange 30 Dye in Supercritical Carbon Dioxide

Jong-Kook Baek, Sunwook Kim¹, Gwang-Soo Lee², and Jae-Jin Shim^†

School of Chemical Engineering and Technology, Yeungnam University, 214-1 Dae-dong, Gyeongsan City, Gyeongbuk 712-749, Korea
¹School of Chemical and Biochemical Engineering, University of Ulsan, San 29, Moogeo-2-dong, Nam-gu, Ulsan 680-749, Korea
²Samill Industries, Ltd., Zone 2 of Seongseo Industrial Complex 2,Daecheon-dong, Dalseo-gu, Daegu 704-329, Korea

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The solubility of C. I. Disperse Orange 30 (O30) dye in CO₂ has been measured by using a closed-loop (batch) solid-fluid equilibrium apparatus at temperatures between 313 and 393 K and at pressures between 11 and 33 MPa. Kumar and Johnston’s equation based on Chrastil’s concept has been used to describe the experimental solubility data. The solubility versus density plot appears much simpler than the solubility versus pressure plot. The isotherms are nearly straight and parallel to each other, as seen in the previous studies. Peng-Robinson equation of state (PR EOS) has also been used successfully in modeling the dye solubility in supercritical carbon dioxide as a function of pressure or density of the fluid phase. The validity of this method has been verified by the vapor pressure calculation.

Keywords:Solubility;Disperse Dye;Supercritical Carbon Dioxide;Peng-Robinson Equation of State

[References]

Baek JK, "Solubility of Disperse Dyes in Supercritical Carbon Dioxide," M.S. Thesis, Yeungnam University (2001)
Bartle KD, Clifford AA, Jafar SA, J. Phys. Chem. Ref. Data, 20, 713 (1991)
Bartle KD, Clifford AA, Shilstone GF, J. Supercrit. Fluids, 5, 220 (1992)
Chang KH, Bae HK, Shim JJ, Korean J. Chem. Eng., 13(3), 310 (1996)
Chrastil J, J. Phys. Chem., 86, 3016 (1982)
Fat'hi MR, Yamini Y, Sharghi H, Shamsipur M, J. Chem. Eng. Data, 43(3), 400 (1998)
Haarhaus U, Swidersky P, Schneider GM, J. Supercrit. Fluids, 8(2), 100 (1995)
Kautz CB, Wagner B, Schneider GM, J. Supercrit. Fluids, 13(1), 43 (1998)
Kumar SK, Johnston KP, J. Supercrit. Fluids, 1, 15 (1988)
Kurnik RT, Reid RC, AIChE J., 27, 861 (1981)
Modell M, Reid RC, Thermodynamics and Tis Applications, Prentice-Hall, Englewood Cliffs, N.J. (1983)
Muthukumaran P, Gupta RB, Sung HD, Shim JJ, Bae HK, Korean J. Chem. Eng., 16(1), 111 (1999)
Ozcan AS, Clifford AA, Bartle KD, Lewis DM, J. Chem. Eng. Data, 42(3), 590 (1997)
Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
Prausnitz JM, Lichtenthaler RN, Azevedo EGD, "Molecular Thermodynamics of Fluid-Phase Equilibria," Prentice-Hall, Upper Saddle River, New Jersey (1999)
Saus W, Knittel D, Schollmeyer E, Text. Res. J., 63, 135 (1993)
Sung HD, M.S. Thesis, Yeungnam University (1998)
Sung HD, Shim JJ, J. Chem. Eng. Data, 44, 985 (1999)
Swidersky P, Tuma D, Schneider GM, J. Supercrit. Fluids, 9(1), 12 (1996)
Tuma D, Schneider GM, J. Supercrit. Fluids, 13(1), 37 (1998)

[Referenced By]

[Related Articles]

[1] Baek JK, "Solubility of Disperse Dyes in Supercritical Carbon Dioxide," M.S. Thesis, Yeungnam University (2001)

[2] Bartle KD, Clifford AA, Jafar SA, J. Phys. Chem. Ref. Data, 20, 713 (1991)

[3] Bartle KD, Clifford AA, Shilstone GF, J. Supercrit. Fluids, 5, 220 (1992)

[4] Chang KH, Bae HK, Shim JJ, Korean J. Chem. Eng., 13(3), 310 (1996)

[5] Chrastil J, J. Phys. Chem., 86, 3016 (1982)

[6] Fat'hi MR, Yamini Y, Sharghi H, Shamsipur M, J. Chem. Eng. Data, 43(3), 400 (1998)

[7] Haarhaus U, Swidersky P, Schneider GM, J. Supercrit. Fluids, 8(2), 100 (1995)

[8] Kautz CB, Wagner B, Schneider GM, J. Supercrit. Fluids, 13(1), 43 (1998)

[9] Kumar SK, Johnston KP, J. Supercrit. Fluids, 1, 15 (1988)

[10] Kurnik RT, Reid RC, AIChE J., 27, 861 (1981)

[11] Modell M, Reid RC, Thermodynamics and Tis Applications, Prentice-Hall, Englewood Cliffs, N.J. (1983)

[12] Muthukumaran P, Gupta RB, Sung HD, Shim JJ, Bae HK, Korean J. Chem. Eng., 16(1), 111 (1999)

[13] Ozcan AS, Clifford AA, Bartle KD, Lewis DM, J. Chem. Eng. Data, 42(3), 590 (1997)

[14] Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)

[15] Prausnitz JM, Lichtenthaler RN, Azevedo EGD, "Molecular Thermodynamics of Fluid-Phase Equilibria," Prentice-Hall, Upper Saddle River, New Jersey (1999)

[16] Saus W, Knittel D, Schollmeyer E, Text. Res. J., 63, 135 (1993)

[17] Sung HD, M.S. Thesis, Yeungnam University (1998)

[18] Sung HD, Shim JJ, J. Chem. Eng. Data, 44, 985 (1999)

[19] Swidersky P, Tuma D, Schneider GM, J. Supercrit. Fluids, 9(1), 12 (1996)

[20] Tuma D, Schneider GM, J. Supercrit. Fluids, 13(1), 37 (1998)