화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.21, No.2, 381-384, March, 2004
Catalytic Composites Based on Yttria Stabilized Zirconia for Oxidative Dehydrogenation of Ethane
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LiCl/YSZ is found to be a very effective catalyst for the oxidative dehydrogenation of ethane. LiCl supported on YSZ-MgO composite shows increase in catalytic activity and ethylene selectivity. Addition of Mn and Sn as promoters to this system leads to 85% ethane conversion, 77% ethylene selectivity and 65% ethylene yield at 662 ℃. Use of Li2O in the place of LiCl results in lower ethylene yields. Further modification is needed to improve the catalyst stability.
  1. Baerns M, Buyevskaya O, Catal. Today, 45(1-4), 13 (1998) 
  2. Banares MA, Catal. Today, 51(2), 319 (1999) 
  3. Cavani F, Trifiro F, Catal. Today, 24(3), 307 (1995) 
  4. Cavani F, Trifiro F, Catal. Today, 51(3-4), 561 (1999) 
  5. Cormway SJ, Wang DJ, Lunsford JH, Appl. Catal. A: Gen., 79, L1 (1991) 
  6. Dai HX, Ng CF, Au CT, Catal. Lett., 57(3), 115 (1999) 
  7. Dow WP, Huang TJ, J. Catal., 160(2), 171 (1996) 
  8. Eastman AD, Kolts J, "Oxidative Dehydrogenation Catalyst," U.S. Patent, 4,370,259 (1983)
  9. Hamakawa S, Sato K, Hayakawa T, York AP, Tsunoda T, Suzuki K, Shimizu M, Takehira K, J. Electrochem. Soc., 144(1), 1 (1997) 
  10. Jackson NB, Ekerdt JG, J. Catal., 126, 31 (1990) 
  11. Jones CA, Loenard JJ, Sofranco JA, "Hydrocarbon Dehydrogenation," U.S. Patent, 4,737,595 (1988)
  12. Kou Y, Zhang B, Niu JZ, Li SB, Wang HL, Tanaka T, Yoshida S, J. Catal., 173(2), 399 (1998) 
  13. Liu Y, Zhang Y, Liu X, Xue J, Li S, Chem. Lett., 1057 (1998) 
  14. Mariscal R, Soria J, Pena MA, Fierro JL, J. Catal., 147(2), 535 (1994) 
  15. Otsuka K, Ando T, Suprapto S, Wang Y, Ebitani K, Yamanaka I, Catal. Today, 24(3), 315 (1995) 
  16. Otsuka K, Hatano M, Komatsu T, Catal. Today, 4, 409 (1989) 
  17. Otsuka K, Liu Q, Hatano M, Morikawa A, Chem. Lett., 903 (1986) 
  18. Pak S, Qiu P, Lunsford JH, J. Catal., 179(1), 222 (1998) 
  19. Seo HJ, Yu EY, Korean J. Chem. Eng., 12(4), 485 (1995)
  20. Silver RG, Hou CJ, Ekerdt JG, J. Catal., 118, 400 (1989) 
  21. Srihiranpullop S, Praserthdam P, Korean J. Chem. Eng., 20(6), 1017 (2003)
  22. Swaan HM, Toebs A, Seshan K, vanOmmen JG, Ross JRH, Catal. Today, 13, 629 (1992) 
  23. vanKeulen ANJ, Hoogardam GC, Seshan K, vanOmmen JG, Ross JRH, J. Chem. Soc.-Chem. Commun., 1546 (1992)
  24. Wang S, Murata K, Hayakawa T, Hamakawa S, Suzuki K, Catal. Lett., 59(2-4), 173 (1999)
  25. Wang SB, Murata K, Hayakawa T, Hamakawa S, Suzuki K, Catal. Lett., 62(2-4), 191 (1999)
  26. Wang S, Murata K, Hayakawa T, Hamakawa S, Suzuki K, Chem. Commun., 103 (1999) 
  27. Wang S, Murata K, Hayakawa K, Hamakawa S, Suzuki K, Stud. Surf. Sci. Catal., 130, 1829 (2000)
  28. Wang DJ, Rosynek MP, Lunsford JH, J. Catal., 151(1), 155 (1995) 
  29. Wang DJ, Rosynek MP, Lunsford JH, Chem. Eng. Technol., 18(2), 118 (1995) 
  30. Guo XM, Hidajat K, Ching CB, Korean J. Chem. Eng., 15(5), 469 (1998)