Sol-Gel법에 의한 Nanoporous Alumina Membrane용 Alumina Sol 제조

박자룡; 김태환; 성재석; 송기창; Ja-Lyong Park; Tae-Hwan Kim; Jae-Suk Sung; Ki-Chang Song

Korean Chemical Engineering Research, Vol.42, No.1, 96-101, February, 2004

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Sol-Gel법에 의한 Nanoporous Alumina Membrane용 Alumina Sol 제조

Preparation of Alumina Sol for Nanoporous Alumina Membrane by Sol-Gel Method

박자룡, 김태환 ¹, 성재석¹, 송기창 ^†

건양대학교 화학공학과, 320-711 충남 논산시 내동 26
¹한국에너지기술연구원 에너지시스템연구부, 305-343 대전시 유성구 장동 71-2

Ja-Lyong Park, Tae-Hwan Kim¹, Jae-Suk Sung¹, and Ki-Chang Song^†

Department of Chemical Engineering, Konyang University, 26, Nae-dong, Nonsan, Chungnam 320-711, Korea
¹Energy System Division, Korea Institute of Energy Research, 71-2, Jang-dong, Yuseong-gu, Daejeon 305-343, Korea

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초록

Sol-Gel법에 의해 출발물질로 aluminum isopropoxide(AIP)를 사용하여, 가수분해 및 해교과정을 거쳐 alumina(boehmite)졸을 제조하였다. 또한 이 졸을 건조오븐에서 건조시켜, 분말을 제조한 후 열처리온도에 따른 분말 결정상의 조성과 기공특성을 조사하였다. 100 ℃에서 열처리하여 제조된 분말은 boehmite상을 나타내었으나, 500 ℃에서 γ-alumina로 상전이 되었다. HCl/AIP=0.10의 조건으로 해교된 후 600 ℃로 열처리된 분말은 4 nm의 평균기공 크기를 나타내었다. 또한 해교시 첨가된 HCl양이 증가됨에 따라 기공의 크기는 감소한 반면 열처리 온도가 증가됨에 따라 평균기공의 크기는 증가하였다.

Alumina (boehmite) sol was prepared by the sol-gel method from aluminum isopropoxide (AIP) through hydrolysis and peptization processes. Powders were obtained by drying the sol in drying oven, and the powder properties, such as crystalline phase composition and pore structure, were studied as a function of heat-treatment temperatures. The powders showed boehmite phase at 100 ℃, and transformed to γ-alumina at 500 ℃. The powders, heat-treated at 600 ℃ after being peptized at HCl/AIP=0.10, had 4 nm in average pore diameter. The average pore diameter of the powders decreased with increasing HCl concentrations added during peptization process, but increased with increasing heat-treatment temperatures.

Keywords:γ-Alumina;Alumina Sol;Aluminum Isopropoxide;Boehmite;Hydrolysis;Pore Diameter;Peptization;Sol-Gel Method

[References]

Pierson HO, "World-Wide Applications and Market Overview of Sol-Gel," Presented at Assessing and Quantifying the Market Impact Sol-Gel Production of High Performance Ceramics and Glasses, December 10-12, Micro Island, Florida (1989)
Uhlhorn RJR, Huis In't Veld MHBJ, Keizer K, Burggraaf AJ, J. Membr. Sci., 46(2-3), 225 (1989)
Hsieh HP, Bhave RR, Fleming HL, J. Membr. Sci., 39(3), 221 (1988)
Uhlhorn RJR, Zaspalis VT, Keizer K, Burggraaf AJ, J. Mater. Sci., 28, 538 (1992)
Gavalas GR, Megiris CE, Nam SW, Chem. Eng. Sci., 44(9), 1928 (1989)
Uemiya S, Sato N, Ando H, Kude Y, Masuda T, Kikuchi E, J. Membr. Sci., 56(3), 315 (1991)
Li ZY, Maeda H, Kusakabe K, Morooka S, Anzai H, Akiyama S, J. Membr. Sci., 78(3), 247 (1993)
Johnson DW, Am. Ceram. Soc. Bull., 54, 286 (1975)
Brinker JC, Scherer GW, Sol-Gel Science, The Physics and Chemistry of Sol-Gel Processing, Academic Press (1990)
Park HJ, "Alumina Coatings on Stainless Steel by the Sol-Gel Method," M.A. Thesis, Yonsei University, Seoul (1987)
Park SE, Kim DS, Hwang YK, Prospect. Ind. Chem., 4(6), 10 (2001)
http://www.IUPAC.org/goldbook/M03853.pdf
Song KC, Chung IJ, J. Non-Cryst. Solids, 107(2), 193 (1989)
Song KC, Chung IJ, J. Non-Cryst. Solids, 108(1), 37 (1989)
Gadsden JA, Infrared Spectra of Minerals and Related Inorganic Compounds, Batterworths, Reading, Mass (1975)
Nakamoto K, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, New York (1978)
Pecharroman C, Gonzalez-Carreno T, Iglesias JE, J. Mater. Res., 11(1), 127 (1996)
Uhlhorn RJR, Keizer K, Burggraaf AJ, J. Mater. Sci., 27, 527 (1992)
Brunauer S, Deming LS, Deming WS, Teller E, J. Am. Chem. Soc., 62, 1723 (1940)
deBoer JH, The Structure and Properties of Porous Materials, Butterworths, Reading, Mass (1975)

[Referenced By]

[Related Articles]

[1] Pierson HO, "World-Wide Applications and Market Overview of Sol-Gel," Presented at Assessing and Quantifying the Market Impact Sol-Gel Production of High Performance Ceramics and Glasses, December 10-12, Micro Island, Florida (1989)

[2] Uhlhorn RJR, Huis In't Veld MHBJ, Keizer K, Burggraaf AJ, J. Membr. Sci., 46(2-3), 225 (1989)

[3] Hsieh HP, Bhave RR, Fleming HL, J. Membr. Sci., 39(3), 221 (1988)

[4] Uhlhorn RJR, Zaspalis VT, Keizer K, Burggraaf AJ, J. Mater. Sci., 28, 538 (1992)

[5] Gavalas GR, Megiris CE, Nam SW, Chem. Eng. Sci., 44(9), 1928 (1989)

[6] Uemiya S, Sato N, Ando H, Kude Y, Masuda T, Kikuchi E, J. Membr. Sci., 56(3), 315 (1991)

[7] Li ZY, Maeda H, Kusakabe K, Morooka S, Anzai H, Akiyama S, J. Membr. Sci., 78(3), 247 (1993)

[8] Johnson DW, Am. Ceram. Soc. Bull., 54, 286 (1975)

[9] Brinker JC, Scherer GW, Sol-Gel Science, The Physics and Chemistry of Sol-Gel Processing, Academic Press (1990)

[10] Park HJ, "Alumina Coatings on Stainless Steel by the Sol-Gel Method," M.A. Thesis, Yonsei University, Seoul (1987)

[11] Park SE, Kim DS, Hwang YK, Prospect. Ind. Chem., 4(6), 10 (2001)

[12] http://www.IUPAC.org/goldbook/M03853.pdf

[13] Song KC, Chung IJ, J. Non-Cryst. Solids, 107(2), 193 (1989)

[14] Song KC, Chung IJ, J. Non-Cryst. Solids, 108(1), 37 (1989)

[15] Gadsden JA, Infrared Spectra of Minerals and Related Inorganic Compounds, Batterworths, Reading, Mass (1975)

[16] Nakamoto K, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, New York (1978)

[17] Pecharroman C, Gonzalez-Carreno T, Iglesias JE, J. Mater. Res., 11(1), 127 (1996)

[18] Uhlhorn RJR, Keizer K, Burggraaf AJ, J. Mater. Sci., 27, 527 (1992)

[19] Brunauer S, Deming LS, Deming WS, Teller E, J. Am. Chem. Soc., 62, 1723 (1940)

[20] deBoer JH, The Structure and Properties of Porous Materials, Butterworths, Reading, Mass (1975)