아크릴아미드 고정 구멍갈파래에 의한 중금속 Cd(II), Pb(II) 이온의 흡착특성(II) - Batch법

박광하; 권영두; 정영진; 장은경; Kwang-Ha Park; Young-Du Kwon; Yeong-Jin Chung; Eung-Kyung Jang

Journal of the Korean Industrial and Engineering Chemistry, Vol.15, No.2, 194-199, April, 2004

Adsorption Characteristics of the Heavy Metals, Cd(II) and Pb(II) Ions, on the Acrylamide-immobilized Ulva pertusa-Batch Method

박광하 ^†, 권영두¹, 정영진 ², 장은경

강릉대학교 환경응용화학공학과, 강릉 210-702
¹동해대학교 환경공학과, 동해 240-713
²삼척대학교 소방방재학부, 삼척 245-711

Kwang-Ha Park^†, Young-Du Kwon¹, Yeong-Jin Chung², and Eung-Kyung Jang

Department of Environmental & Applied Chemical Engineering, Kangnung National University, Kangnung 210-702, Korea
¹Department of Environmental Engineering, Donghae University, Donghae 240-713, Korea
²Department of Fire & Diaster Protection Engineering, Samcheok National University, Samcheok 245-711, Korea

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초록

본 연구에서는 동해안 해조류인 구멍갈파래를 아크릴아미드에 고정하여, Cd(II) 및 Pb(II) 중금속 이온의 흡착 특성을 살펴보았다. Batch법에 의해 진탕시간, 농도 및 pH를 변화시켜가면서 흡착속도를 측정하였다. Batch법에서 중금속 흡착량은 pH 10.5 > 7.0 > 3.5 순으로 나타났으며, 이는 기발표된 Column법의 결과와 동일한 경향을 보였다. 또한 Pb(II)이온이 Cu(II)이온보다 많은 양이 쉽게 흡착되는 것으로 나타났으며, 모든 pH 영역에서 흡착속도는 20 min이내에 최대값을 보이는 것으로 나타났다.

Adsorption characteristics of Cd(II) and Pb(II) heavy metal ions onto the acrylamide-immobilized Ulva pertusa, an algae of the eastern coastal area, were examined inthis work. Adsorption rate was determined by modulating shaking time, concentration, and pH in the batch method. It was observed that the adsorption amounts of heavy metal ions in batch method was in the following order of pH 10.5 > 7.0 > 3.5, in good agreement with trend reported previously in column method. It was also revealed that Pb(II) was more readily adsorbed on the algae that Cu(II), and that adsorption amounts showed maximum within 20 minutes all over the pH range.

Keywords:acrylamide-Ulva pertusa;adsorption;recovery;heavy metal;batch method

[References]

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Bolto BA, Pawlowski L, J. W. Arrowsnith Ltd., New York (1987)
Kunz RG, Giannelli JF, Stensel HD, J. WPCF, 48(4), 762 (1976)
Hassler WW, West Virginia Pulp and Pater Co., New York (1947)
Brady D, Stoll A, Duncan FR, Environ. Technol., 15, 428 (1994)
Sami FE, Abdel HJ, J. Microbiol., 1(21), 263 (1983)
Skowronski T, Przytocka M, Chemosphere, 15, 77 (1983)
Yu QM, Kaewsarn P, Ma WD, Matheickal JT, Yin PH, Chin. J. Chem. Eng., 9(2), 133 (2001)
Darnall DW, Greene B, Hosea H, McPherson RA, Henzl M, Recovery of Heavy Metals by Immobilized Algae, The Royal Society of Chemistry, Special Publication, London, 61, 1 (1986)
Matheickal JT, Yu QM, Bioresour. Technol., 69(3), 223 (1999)
Crist RH, Oberholser K, Shank N, Nguyen M, Environ. Sci. Technol., 15, 1212 (1981)
Robinson NJ, J. Appl. Physcol., 1, 5 (1989)
Pavicic J, Raspor B, Martincic D, Marine Biology, 115, 435 (1993)
Robinson NJ, Jackson PJ, Physiol. Plant., 67, 499 (1986)
Wikfors GH, Neeman A, Jackson PJ, Mar. Ecol. Prog. Ser., 79, 163 (1991)
Bebianno MJ, Langston WJ, Marine Biology, 108, 91 (1991)
Gupta SC, Goldsrough PB, Plant Physiol., 97, 306 (1991)
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Davison IR, Reed RH, Phycologia, 24, 449 (1985)
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Masri MS, Friedman M, Environ. Sci. Technol., 7(10) (1973)
Harris PO, Ramelow GJ, Environ. Sci. Technol., 24, 220 (1990)
Khummongkol D, Canterford GS, Freyer C, Biotechnol. Bioeng., 24, 2643 (1982)
Crist RH, Oberholser K, Shank N, Nguyen M, Environ. Sci. Technol., 15, 1212 (1981)
Aksu Z, Kutsal T, Environ. Technol., 11(10), 979 (1990)
Lee HS, Suh KH, Suh JH, J. Korean Fish. Soc., 33(1), 60 (2000)
Suh KH, An KH, Lee HS, J. Korean Fish. Soc., 32(4), 399 (1999)
Darnall DW, WRRI Report, 125 (1996)
Guibal E, Roulph C, Cloirec PL, Water Res., 26(8), 1139 (1992)
Fourest E, Roux JC, Appl. Microbiol. Biotechnol., 37(3), 399 (1992)
Lujan JR, Darnall DW, Stark PC, Rayson GD, Gardea JL, Sol. Extraction Ion Exchange, 12(4), 803 (1994)
Park KH, Park MA, Kim YH, Choi BJ, Anal. Sci. Technol., 12(2), 121 (1999)

[Related Articles]

[1] Jon GD, Frank LB, Environ. Sci. Technol., 6, 518 (1972)

[2] Bolto BA, Pawlowski L, J. W. Arrowsnith Ltd., New York (1987)

[3] Kunz RG, Giannelli JF, Stensel HD, J. WPCF, 48(4), 762 (1976)

[4] Hassler WW, West Virginia Pulp and Pater Co., New York (1947)

[5] Brady D, Stoll A, Duncan FR, Environ. Technol., 15, 428 (1994)

[6] Sami FE, Abdel HJ, J. Microbiol., 1(21), 263 (1983)

[7] Skowronski T, Przytocka M, Chemosphere, 15, 77 (1983)

[8] Yu QM, Kaewsarn P, Ma WD, Matheickal JT, Yin PH, Chin. J. Chem. Eng., 9(2), 133 (2001)

[9] Darnall DW, Greene B, Hosea H, McPherson RA, Henzl M, Recovery of Heavy Metals by Immobilized Algae, The Royal Society of Chemistry, Special Publication, London, 61, 1 (1986)

[10] Matheickal JT, Yu QM, Bioresour. Technol., 69(3), 223 (1999)

[11] Crist RH, Oberholser K, Shank N, Nguyen M, Environ. Sci. Technol., 15, 1212 (1981)

[12] Robinson NJ, J. Appl. Physcol., 1, 5 (1989)

[13] Pavicic J, Raspor B, Martincic D, Marine Biology, 115, 435 (1993)

[14] Robinson NJ, Jackson PJ, Physiol. Plant., 67, 499 (1986)

[15] Wikfors GH, Neeman A, Jackson PJ, Mar. Ecol. Prog. Ser., 79, 163 (1991)

[16] Bebianno MJ, Langston WJ, Marine Biology, 108, 91 (1991)

[17] Gupta SC, Goldsrough PB, Plant Physiol., 97, 306 (1991)

[18] Xue HB, Stumm W, Sigg L, Water Res., 22(7), 917 (1988)

[19] Henderson RW, Andrews DS, Lightsey GR, Poonawala NA, Bull. Environ. Contam. Toxicol., 17, 355 (1976)

[20] Davison IR, Reed RH, Phycologia, 24, 449 (1985)

[21] Tsezos M, Horikohi TJ, Appl. Microbiol., 16, 88 (1982)

[22] Masri MS, Friedman M, Environ. Sci. Technol., 7(10) (1973)

[23] Harris PO, Ramelow GJ, Environ. Sci. Technol., 24, 220 (1990)

[24] Khummongkol D, Canterford GS, Freyer C, Biotechnol. Bioeng., 24, 2643 (1982)

[25] Crist RH, Oberholser K, Shank N, Nguyen M, Environ. Sci. Technol., 15, 1212 (1981)

[26] Aksu Z, Kutsal T, Environ. Technol., 11(10), 979 (1990)

[27] Lee HS, Suh KH, Suh JH, J. Korean Fish. Soc., 33(1), 60 (2000)

[28] Suh KH, An KH, Lee HS, J. Korean Fish. Soc., 32(4), 399 (1999)

[29] Darnall DW, WRRI Report, 125 (1996)

[30] Guibal E, Roulph C, Cloirec PL, Water Res., 26(8), 1139 (1992)

[31] Fourest E, Roux JC, Appl. Microbiol. Biotechnol., 37(3), 399 (1992)

[32] Lujan JR, Darnall DW, Stark PC, Rayson GD, Gardea JL, Sol. Extraction Ion Exchange, 12(4), 803 (1994)

[33] Park KH, Park MA, Kim YH, Choi BJ, Anal. Sci. Technol., 12(2), 121 (1999)