활성탄에 대한 말토올리고당의 흡착평형

이재욱; 정흥조; 문희; 문일식

HWAHAK KONGHAK, Vol.37, No.6, 890-896, December, 1999

Export Citation

활성탄에 대한 말토올리고당의 흡착평형

Adsorption Equilibria of Maltooligosaccharides on Activated Carbon

이재욱, 정흥조, 문희, 문일식

초록

수용액으로부터 용존하는 혼합 말토올리고당의 분리 및 순도를 향상시키기 위한 기초연구로서 국내산 활성탄에 대한 말토올리고당의 흡착평형을 다루었다. 활성탄에 대한 단일성분의 흡착등온식은 Langmuir, Freundich 및 Sip식을 사용하여 나타내었고 다성분 흡착량은 확장된 Langmuir 등온식(extended Langmuir isotherm), 확장된 Langmuir-Freundlich 등온식(extended Langmuir-Freundlich isotherm) 및 이상용액이론(ideal adsorbed solution theory)을 사용하여 예측하였다.

Adsorption equilibrium of maltooligosaccharides on activated carbon was studied as a separation and purification method for maltooligosaccharids dissolved in aqueous solutions. Single-species isotherms were represented by the Langextended Langmuir-Freundlich isotherm(ELFI), and ideal adsorbed solution theory(IAST)

Keywords:Activated Carbon;Adsorption;Maltooligosaccharides;Multicomponent Equilibria

[References]

Vihinen M, Mantsala P, Crit. Rev. Biochem. Mol. Biol., 24, 329 (1989)
Dziezak JD, Food Technol., 45, 78 (1991)
Kwon TW, Lee JW, Cho GJ, Ahn HG, Moon IS, Theor. Appl. Chem. Eng., 4, 601 (1998)
Lee JW, Jung HJ, Moon H, Korean J. Chem. Eng., 14(4), 277 (1997)
Shim WG, Lee JW, Moon H, Korean J. Chem. Eng., 15(3), 297 (1998)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Freundlich H, Trans. Faraday Soc., 28, 195 (1932)
Sips RJ, J. Chem. Phys., 18, 1024 (1950)
Moon H, Kook SK, Park HC, Korean J. Chem. Eng., 8(3), 168 (1991)
Rudzinski W, Everett DH, "Adsorption of Gases on Heterogeneous Surfaces," Academic Press, London (1994)
Yang RT, "Gas Separation by Adsorption Processes," Butterworths, Boston (1987)
Myers AL, Prausnitz JM, AIChE J., 11, 121 (1965)
Suwanayuen S, Danner RP, AIChE J., 26, 68 (1980)
Yon CM, Turnlock PH, C.E.P. Symp. Ser., 67, 75 (1971)
Lee JW, Park HC, Moon H, Sep. Purif. Technol., 12(1), 6 (1997)
Tien C, "Adsorption Calculation and Modeling," Butterworth, Boston (1994)
Abe I, Hayashi K, Kitagawa M, Carbon, 21(3), 189 (1983)
Lourvanij K, Rorrer GL, Appl. Catal. A: Gen., 109(1), 147 (1994)
Ruthven DM, "Principles of Adsorption and Adsorption Processes," John Wiley & Sons (1984)

[Referenced By]

[1] Vihinen M, Mantsala P, Crit. Rev. Biochem. Mol. Biol., 24, 329 (1989)

[2] Dziezak JD, Food Technol., 45, 78 (1991)

[3] Kwon TW, Lee JW, Cho GJ, Ahn HG, Moon IS, Theor. Appl. Chem. Eng., 4, 601 (1998)

[4] Lee JW, Jung HJ, Moon H, Korean J. Chem. Eng., 14(4), 277 (1997)

[5] Shim WG, Lee JW, Moon H, Korean J. Chem. Eng., 15(3), 297 (1998)

[6] Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)

[7] Freundlich H, Trans. Faraday Soc., 28, 195 (1932)

[8] Sips RJ, J. Chem. Phys., 18, 1024 (1950)

[9] Moon H, Kook SK, Park HC, Korean J. Chem. Eng., 8(3), 168 (1991)

[10] Rudzinski W, Everett DH, "Adsorption of Gases on Heterogeneous Surfaces," Academic Press, London (1994)

[11] Yang RT, "Gas Separation by Adsorption Processes," Butterworths, Boston (1987)

[12] Myers AL, Prausnitz JM, AIChE J., 11, 121 (1965)

[13] Suwanayuen S, Danner RP, AIChE J., 26, 68 (1980)

[14] Yon CM, Turnlock PH, C.E.P. Symp. Ser., 67, 75 (1971)

[15] Lee JW, Park HC, Moon H, Sep. Purif. Technol., 12(1), 6 (1997)

[16] Tien C, "Adsorption Calculation and Modeling," Butterworth, Boston (1994)

[17] Abe I, Hayashi K, Kitagawa M, Carbon, 21(3), 189 (1983)

[18] Lourvanij K, Rorrer GL, Appl. Catal. A: Gen., 109(1), 147 (1994)

[19] Ruthven DM, "Principles of Adsorption and Adsorption Processes," John Wiley & Sons (1984)