The grafting of glycidyl methacrylate (GMA) onto linear low-density polyethylene (LLDPE) was investigated. The grafting was performed by free-radical grafting in the melt state in a twin-screw extruder using an organic peroxide as initiator. The effect of initial GMA and peroxide concentration, styrene comonomer addition, as well as initial resin viscosity, on the final content in grafted moieties, unbound homopolymer, and unreacted monomer was assessed. The effect of process parameters such as flow rate, screw rotation speed, and barrel temperature was also investigated. Chemical composition was shown to be the main parameter for controlling grafting level and grafting efficiency. Grafting levels up to 1.8% and efficiency of 90% were reported even though in most conditions, the graft efficiency was severely decreased by the homopolymerization of GMA into polyGMA chains not bound to LLDPE. Finally, the effect of grafting level and the presence of unbound GMA-based species on the efficiency GMA-grafted LLDPE as adhesive between polyethylene and polyester were discussed. Good adhesion to poly(ethylene terephthalate) copolymer was found for low viscosity grafted polyethylene resins. A significant improvement in adhesive strength on polyester was observed when the molecular weight of the grafted LLDPE was increased. (C) 2004 Wiley Periodicals, Inc.