Metal complexes composed of ZnCl2 and bidentate 1,2-bis(2-methyl-5-(4-pyridyl)-3-thienyl)perfluorocyclopentene (1a) and monodentate 1-(2-methyl-5-phenyl-3-thienyl)-2-(2-methyl-5-(4-pyridyl)-3thienyl)perfl uorocyclopentene(2a) photochromic ligands were prepared. X-ray crystallographic analyses showed the formation of a coordination polymer and a discrete 2:1 complex for 1a(.)ZnCl(2) and 2a(2)(.)ZnCl(2), respectively. While the 2a(2)(.)ZnCl(2) crystal underwent photochromic reaction in the crystalline state by alternate irradiation with UV and visible light, the 1a(.)ZnCl(2) crystal did not show any photoreactivity. The difference in the photochromic behavior was explained by the difference in the conformation of the diarylethenes in the crystals.