New thermally stable conducting materials can be obtained by dispersing conducting carbon black into poly(4,4'-diphenylether-1,3,4-oxadiazole) (POD-DPE) solution in NMP. The blend preparation process resulted in quite good dispersed composite and a relatively low percolation 0 threshold (around 5 wt % of CB). The effect of the compressive stress on the resistivity of composite has been evaluated. The resistivity decreases continuously as the applied pressure is increased. In addition to the electrical conductity, the presence of carbon black resulted in higher thermally stable materials. The thermal stability, electrical conductivity, and pressure-sensible characteristics make this conducting material a good candidate for application in manufacture of pressure sensors for high temperature ambient. This material shows a typical semiconductor behavior, characterized by an increase of conductivity with the temperature. (C) 2004 Wiley Periodicals, Inc.