화학공학소재연구정보센터
Journal of Chemical Physics, Vol.121, No.6, 2701-2710, 2004
UV spectra of benzene isotopomers and dimers in helium nanodroplets
We report spectra of various benzene isotopomers and their dimers in helium nanodroplets in the region of the first Herzberg-Teller allowed vibronic transition 6(0)(1) B-1(2u)<--(1)A(1g) (the A(0)(0) transition) at similar to260 nm. Excitation spectra have been recorded using both beam depletion detection and laser-induced fluorescence. Unlike for many larger aromatic molecules, the monomer spectra consist of a single "zero-phonon" line, blueshifted by similar to30 cm(-1) from the gas phase position. Rotational band simulations show that the moments of inertia of C6H6 in the nanodroplets are at least six-times larger than in the gas phase. The dimer spectra present the same vibronic fine structure (though modestly compressed) as previously observed in the gas phase. The fluorescence lifetime and quantum yield of the dimer are found to be equal to those of the monomer, implying substantial inhibition of excimer formation in the dimer in helium. (C) 2004 American Institute of Physics.