화학공학소재연구정보센터
Canadian Journal of Chemical Engineering, Vol.81, No.6, 1215-1221, 2003
Amplification of periodic temperature disturbances in a packed-bed reactor: CO oxidation over a CuO/Al2O3 catalyst
Amplification of periodic variations of input temperature in a product-inhibited reaction - CO oxidation over CuO-gamma-Al2O3 - was investigated experimentally in an insulated packed-bed reactor. At steady state the temperature profile was elongated compared with that of a reactant-inhibited CO oxidation over Pt/Al2O3, studied elsewhere. Under periodic operation, amplitudes of the resulting travelling temperature waves, monitored downstream from the reaction front, were amplified to a greater extent than those in the reactant-inhibited CO oxidation over Pt/Al2O3. The magnitude of the amplification depended on the perturbation frequency and showed resonance behaviour. The magnitude decreased monotonically with increasing perturbation amplitude.