Catalysis Letters, Vol.91, No.1-2, 11-17, 2003
Methane conversion to synthesis gas by partial oxidation and CO2 reforming over supported platinum catalysts
Partial oxidation of methane and reforming of methane with CO2 were carried out with Pt/Al2O3, PtZrO2 and Pt/CeO2 catalysts, in the temperature range of 350 - 900 degreesC. For partial oxidation, the catalysts showed similar stabilities, with the PtZr slightly more active. The reaction occurs in two simultaneous stages: total combustion of methane and reforming of the unconverted methane with steam and CO2, with the O-2 conversion of 100% over the whole temperature range. For reforming with CO2, the catalysts presented similar activities, but with distinct deactivation rates: while the PtAl deactivates very fast at 800 degreesC, due to deposition of inactive carbon, the PtZr and PtCe catalysts offer higher resistance to coke formation, due to the metal-support interactions and the higher mobility of oxygen in the oxide lattice.