화학공학소재연구정보센터
Fluid Phase Equilibria, Vol.216, No.1, 183-186, 2004
On the calculation of the critical temperature from the second virial coefficient
A perturbed virial expansion (expansion in powers of density about a suitable reference fluid) is used to locate the fluid critical point. It is shown that. unlike the case for the usual virial expansion, knowledge of the second virial coefficient alone is sufficient to obtain a reasonably accurate estimate for the critical temperature of both model and real fluids. (C) 2003 Elsevier B.V. All rights reserved.