화학공학소재연구정보센터
Journal of Vacuum Science & Technology B, Vol.22, No.3, 1179-1183, 2004
Oxide formation during ion bombardment of small silicon structures
The kinetics of high dose oxygen implantation and of surface sputtering in silicon are investigated by atomic force microscopy, transmission electron microscopy, transmission electron holography, and electron energy-loss spectroscopy. The implantation was performed into accurately defined submicrometer areas. The behavior of the erosion rate as a function of the implantation dose proved to be nonmonotonic. After native oxide sputtering, a period dominated by (i) implantation of oxygen and (ii) induced oxide formation with volume increase takes place, causing a maximum surface step around the bombarded area of about 1.1 to 1.3 nm at bombardment doses below 2 x 10(16) O+ cm(-2). Subsequently, higher doses cause a sputtering of the surface with a sputter yield of about 0.32 Si atoms/O+. Electron holography revealed the double layer character of the implanted region, and electron energy-loss spectroscopy, especially near the relevant Si-L-23 ionization edge, identified these two layers which are (i) amorphous silicon oxide and (ii) amorphized silicon. Electron energy-loss line scans show the oxygen distribution inside the implanted areas with a lateral resolution of about 1-2 nm. It was found that the interface between the oxidized layer and the amorphized silicon sharpens with increasing implantation dose. (C) 2004 American Vacuum Society.