Journal of Chemical Physics, Vol.121, No.8, 3434-3437, 2004
On the role of coupling in mode selective excitation using ultrafast pulse shaping in stimulated Raman spectroscopy
The coherence of two coupled two-level systems, representing vibrational modes in a semiclassical model, is calculated in weak and strong fields for various coupling schemes and for different relative phases between initial state amplitudes. A relative phase equal to pi projects the system into a dark state. The selective excitation of one of the two, two-level systems is studied as a function of coupling strength and initial phases. (C) 2004 American Institute of Physics.